2,2′-Dimethyl-2,2′-(m-phenyl­ene­dimethyl­ene)propane­dinitrile

The title compound, C(16)H(14)N(4), features an aromatic ring with two 2,2′-dicyano­propyl residues in positions 1 and 3, which are located above and below the ring plane. The two residues differ in their conformation with respect to the aromatic ring: whereas one of the C(meth­yl)—C—C(methyl­ene)—C...

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Detalles Bibliográficos
Autores principales: Zhao, Junmei, Böhmer, Volker, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969357/
https://www.ncbi.nlm.nih.gov/pubmed/21582920
http://dx.doi.org/10.1107/S1600536809023344
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author Zhao, Junmei
Böhmer, Volker
Bolte, Michael
author_facet Zhao, Junmei
Böhmer, Volker
Bolte, Michael
author_sort Zhao, Junmei
collection PubMed
description The title compound, C(16)H(14)N(4), features an aromatic ring with two 2,2′-dicyano­propyl residues in positions 1 and 3, which are located above and below the ring plane. The two residues differ in their conformation with respect to the aromatic ring: whereas one of the C(meth­yl)—C—C(methyl­ene)—C(aromatic) torsion angles is gauche [68.93 (12)°], the other one is fully staggered [177.63 (9)°]. The crystal structure is stabilized by C—H⋯N hydrogen-bonding inter­actions.
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spelling pubmed-29693572010-12-30 2,2′-Dimethyl-2,2′-(m-phenyl­ene­dimethyl­ene)propane­dinitrile Zhao, Junmei Böhmer, Volker Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(14)N(4), features an aromatic ring with two 2,2′-dicyano­propyl residues in positions 1 and 3, which are located above and below the ring plane. The two residues differ in their conformation with respect to the aromatic ring: whereas one of the C(meth­yl)—C—C(methyl­ene)—C(aromatic) torsion angles is gauche [68.93 (12)°], the other one is fully staggered [177.63 (9)°]. The crystal structure is stabilized by C—H⋯N hydrogen-bonding inter­actions. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969357/ /pubmed/21582920 http://dx.doi.org/10.1107/S1600536809023344 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhao, Junmei
Böhmer, Volker
Bolte, Michael
2,2′-Dimethyl-2,2′-(m-phenyl­ene­dimethyl­ene)propane­dinitrile
title 2,2′-Dimethyl-2,2′-(m-phenyl­ene­dimethyl­ene)propane­dinitrile
title_full 2,2′-Dimethyl-2,2′-(m-phenyl­ene­dimethyl­ene)propane­dinitrile
title_fullStr 2,2′-Dimethyl-2,2′-(m-phenyl­ene­dimethyl­ene)propane­dinitrile
title_full_unstemmed 2,2′-Dimethyl-2,2′-(m-phenyl­ene­dimethyl­ene)propane­dinitrile
title_short 2,2′-Dimethyl-2,2′-(m-phenyl­ene­dimethyl­ene)propane­dinitrile
title_sort 2,2′-dimethyl-2,2′-(m-phenyl­ene­dimethyl­ene)propane­dinitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969357/
https://www.ncbi.nlm.nih.gov/pubmed/21582920
http://dx.doi.org/10.1107/S1600536809023344
work_keys_str_mv AT zhaojunmei 22dimethyl22mphenylenedimethylenepropanedinitrile
AT bohmervolker 22dimethyl22mphenylenedimethylenepropanedinitrile
AT boltemichael 22dimethyl22mphenylenedimethylenepropanedinitrile

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