catena-Poly[[(ethanol-κO)sodium(I)]-di-μ-aqua-[(rac-2′-hydr­oxy-1,1′-binaphthyl-2-yl phosphato-κO)sodium]-tri-μ-aqua]

The asymmetric unit of the polymeric title compound, [Na(2)(C(20)H(13)O(5)P)(C(2)H(6)O)(H(2)O)(5)](n), consists of two Na(I) ions, one 2′-hydr­oxy-1,1′-binaphthyl-2-yl phosphate anion, one ethanol ligand and five water molecules of crysallization. Each Na(I) ion has a distorted octa­hedral coordinat...

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Detalles Bibliográficos
Autores principales: Tachibana, Yuya, Maeda, Yasukatsu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969360/
https://www.ncbi.nlm.nih.gov/pubmed/21582689
http://dx.doi.org/10.1107/S1600536809021394
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author Tachibana, Yuya
Maeda, Yasukatsu
author_facet Tachibana, Yuya
Maeda, Yasukatsu
author_sort Tachibana, Yuya
collection PubMed
description The asymmetric unit of the polymeric title compound, [Na(2)(C(20)H(13)O(5)P)(C(2)H(6)O)(H(2)O)(5)](n), consists of two Na(I) ions, one 2′-hydr­oxy-1,1′-binaphthyl-2-yl phosphate anion, one ethanol ligand and five water molecules of crysallization. Each Na(I) ion has a distorted octa­hedral coordination geometry. The phosphate anion coordinates to one Na(I) ion and the ethanol mol­ecule coordinates to the other. The five water mol­ecules bridge the Na(I) ions, forming an inorganic chain structure along the b axis. The chains are connected by O—H⋯O hydrogen bonds into an organic–inorganic hybrid layer parallel to (001).
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spelling pubmed-29693602010-12-30 catena-Poly[[(ethanol-κO)sodium(I)]-di-μ-aqua-[(rac-2′-hydr­oxy-1,1′-binaphthyl-2-yl phosphato-κO)sodium]-tri-μ-aqua] Tachibana, Yuya Maeda, Yasukatsu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the polymeric title compound, [Na(2)(C(20)H(13)O(5)P)(C(2)H(6)O)(H(2)O)(5)](n), consists of two Na(I) ions, one 2′-hydr­oxy-1,1′-binaphthyl-2-yl phosphate anion, one ethanol ligand and five water molecules of crysallization. Each Na(I) ion has a distorted octa­hedral coordination geometry. The phosphate anion coordinates to one Na(I) ion and the ethanol mol­ecule coordinates to the other. The five water mol­ecules bridge the Na(I) ions, forming an inorganic chain structure along the b axis. The chains are connected by O—H⋯O hydrogen bonds into an organic–inorganic hybrid layer parallel to (001). International Union of Crystallography 2009-06-10 /pmc/articles/PMC2969360/ /pubmed/21582689 http://dx.doi.org/10.1107/S1600536809021394 Text en © Tachibana and Maeda 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tachibana, Yuya
Maeda, Yasukatsu
catena-Poly[[(ethanol-κO)sodium(I)]-di-μ-aqua-[(rac-2′-hydr­oxy-1,1′-binaphthyl-2-yl phosphato-κO)sodium]-tri-μ-aqua]
title catena-Poly[[(ethanol-κO)sodium(I)]-di-μ-aqua-[(rac-2′-hydr­oxy-1,1′-binaphthyl-2-yl phosphato-κO)sodium]-tri-μ-aqua]
title_full catena-Poly[[(ethanol-κO)sodium(I)]-di-μ-aqua-[(rac-2′-hydr­oxy-1,1′-binaphthyl-2-yl phosphato-κO)sodium]-tri-μ-aqua]
title_fullStr catena-Poly[[(ethanol-κO)sodium(I)]-di-μ-aqua-[(rac-2′-hydr­oxy-1,1′-binaphthyl-2-yl phosphato-κO)sodium]-tri-μ-aqua]
title_full_unstemmed catena-Poly[[(ethanol-κO)sodium(I)]-di-μ-aqua-[(rac-2′-hydr­oxy-1,1′-binaphthyl-2-yl phosphato-κO)sodium]-tri-μ-aqua]
title_short catena-Poly[[(ethanol-κO)sodium(I)]-di-μ-aqua-[(rac-2′-hydr­oxy-1,1′-binaphthyl-2-yl phosphato-κO)sodium]-tri-μ-aqua]
title_sort catena-poly[[(ethanol-κo)sodium(i)]-di-μ-aqua-[(rac-2′-hydr­oxy-1,1′-binaphthyl-2-yl phosphato-κo)sodium]-tri-μ-aqua]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969360/
https://www.ncbi.nlm.nih.gov/pubmed/21582689
http://dx.doi.org/10.1107/S1600536809021394
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AT maedayasukatsu catenapolyethanolkosodiumidimaquarac2hydroxy11binaphthyl2ylphosphatokosodiumtrimaqua

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