Bis[μ(2)-N′-acetyl-2-hydroxy-6-oxido­benzohydrazidato(3−)]octa­pyridine­trinickel(II)

The title trinuclear complex, [Ni(3)(C(9)H(7)N(2)O(4))(2)(C(5)H(5)N)(8)], possesses a crystallographically imposed center of symmetry occupied by one Ni(II) ion. Each of the three Ni(II) ions is coordinated by two O and four N atoms, respectively, in a distorted octa­hedral geometry. In the crystal,...

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Detalles Bibliográficos
Autores principales: Yang, Yan, Li, Dacheng, Shi, Xuefeng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969366/
https://www.ncbi.nlm.nih.gov/pubmed/21582684
http://dx.doi.org/10.1107/S1600536809020534
Descripción
Sumario:The title trinuclear complex, [Ni(3)(C(9)H(7)N(2)O(4))(2)(C(5)H(5)N)(8)], possesses a crystallographically imposed center of symmetry occupied by one Ni(II) ion. Each of the three Ni(II) ions is coordinated by two O and four N atoms, respectively, in a distorted octa­hedral geometry. In the crystal, weak inter­molecular C—H⋯π inter­actions link the mol­ecules into ribbons propagating in the [100] direction.

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