N′-(5-Bromo-2-methoxy­benzyl­idene)-4-hydroxy­benzohydrazide methanol solvate

In the title hydrazone compound, C(15)H(13)BrN(2)O(3)·CH(3)OH, the methanol solvate is linked to the benzohydrazide molecule through O—H⋯N and O—H⋯O hydrogen bonds. The benzohydrazide mol­ecule adopts an E configuration about the C=N double bond. The mol­ecule is twisted, with a dihedral angle betwe...

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Detalles Bibliográficos
Autores principales: Lin, Xue-Song, Sang, Ya-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969367/
https://www.ncbi.nlm.nih.gov/pubmed/21582914
http://dx.doi.org/10.1107/S1600536809022983
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author Lin, Xue-Song
Sang, Ya-Li
author_facet Lin, Xue-Song
Sang, Ya-Li
author_sort Lin, Xue-Song
collection PubMed
description In the title hydrazone compound, C(15)H(13)BrN(2)O(3)·CH(3)OH, the methanol solvate is linked to the benzohydrazide molecule through O—H⋯N and O—H⋯O hydrogen bonds. The benzohydrazide mol­ecule adopts an E configuration about the C=N double bond. The mol­ecule is twisted, with a dihedral angle between the two substituted benzene rings of 35.7 (2)°. In the crystal structure, mol­ecules are linked through inter­molecular N—H⋯O and O—H⋯O hydrogen bonds, forming layers parallel to the ac plane.
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spelling pubmed-29693672010-12-30 N′-(5-Bromo-2-methoxy­benzyl­idene)-4-hydroxy­benzohydrazide methanol solvate Lin, Xue-Song Sang, Ya-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrazone compound, C(15)H(13)BrN(2)O(3)·CH(3)OH, the methanol solvate is linked to the benzohydrazide molecule through O—H⋯N and O—H⋯O hydrogen bonds. The benzohydrazide mol­ecule adopts an E configuration about the C=N double bond. The mol­ecule is twisted, with a dihedral angle between the two substituted benzene rings of 35.7 (2)°. In the crystal structure, mol­ecules are linked through inter­molecular N—H⋯O and O—H⋯O hydrogen bonds, forming layers parallel to the ac plane. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969367/ /pubmed/21582914 http://dx.doi.org/10.1107/S1600536809022983 Text en © Lin and Sang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lin, Xue-Song
Sang, Ya-Li
N′-(5-Bromo-2-methoxy­benzyl­idene)-4-hydroxy­benzohydrazide methanol solvate
title N′-(5-Bromo-2-methoxy­benzyl­idene)-4-hydroxy­benzohydrazide methanol solvate
title_full N′-(5-Bromo-2-methoxy­benzyl­idene)-4-hydroxy­benzohydrazide methanol solvate
title_fullStr N′-(5-Bromo-2-methoxy­benzyl­idene)-4-hydroxy­benzohydrazide methanol solvate
title_full_unstemmed N′-(5-Bromo-2-methoxy­benzyl­idene)-4-hydroxy­benzohydrazide methanol solvate
title_short N′-(5-Bromo-2-methoxy­benzyl­idene)-4-hydroxy­benzohydrazide methanol solvate
title_sort n′-(5-bromo-2-methoxy­benzyl­idene)-4-hydroxy­benzohydrazide methanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969367/
https://www.ncbi.nlm.nih.gov/pubmed/21582914
http://dx.doi.org/10.1107/S1600536809022983
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AT sangyali n5bromo2methoxybenzylidene4hydroxybenzohydrazidemethanolsolvate

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