(4-Chloro­benzohydrazidato-κ(2) N′,O)[2-(4-chloro­benzoyl­hydrazono-κ(2) N,O)propionato(2−)-κO]oxidovanadium(V)

In the crystal structure of the title compound, [VO(C(7)H(6)ClN(2)O)(C(10)H(7)ClN(2)O(3))], the V(V) atom is N,O-chelated by the chloro­benzoyl­hydrazidate anion and O,N,O′-chelated by the (chloro­benzoyl­hydrazono)propionate dianion. The distorted octa­hedral trans-N(2)O(4) coordination geometry is...

Descripción completa

Detalles Bibliográficos
Autores principales: Wong, Hon Wee, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969368/
https://www.ncbi.nlm.nih.gov/pubmed/21582662
http://dx.doi.org/10.1107/S1600536809019928
_version_ 1782190128133832704
author Wong, Hon Wee
Lo, Kong Mun
Ng, Seik Weng
author_facet Wong, Hon Wee
Lo, Kong Mun
Ng, Seik Weng
author_sort Wong, Hon Wee
collection PubMed
description In the crystal structure of the title compound, [VO(C(7)H(6)ClN(2)O)(C(10)H(7)ClN(2)O(3))], the V(V) atom is N,O-chelated by the chloro­benzoyl­hydrazidate anion and O,N,O′-chelated by the (chloro­benzoyl­hydrazono)propionate dianion. The distorted octa­hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds into a linear chain parallel to [010].
format Text
id pubmed-2969368
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29693682010-12-30 (4-Chloro­benzohydrazidato-κ(2) N′,O)[2-(4-chloro­benzoyl­hydrazono-κ(2) N,O)propionato(2−)-κO]oxidovanadium(V) Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [VO(C(7)H(6)ClN(2)O)(C(10)H(7)ClN(2)O(3))], the V(V) atom is N,O-chelated by the chloro­benzoyl­hydrazidate anion and O,N,O′-chelated by the (chloro­benzoyl­hydrazono)propionate dianion. The distorted octa­hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds into a linear chain parallel to [010]. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969368/ /pubmed/21582662 http://dx.doi.org/10.1107/S1600536809019928 Text en © Wong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wong, Hon Wee
Lo, Kong Mun
Ng, Seik Weng
(4-Chloro­benzohydrazidato-κ(2) N′,O)[2-(4-chloro­benzoyl­hydrazono-κ(2) N,O)propionato(2−)-κO]oxidovanadium(V)
title (4-Chloro­benzohydrazidato-κ(2) N′,O)[2-(4-chloro­benzoyl­hydrazono-κ(2) N,O)propionato(2−)-κO]oxidovanadium(V)
title_full (4-Chloro­benzohydrazidato-κ(2) N′,O)[2-(4-chloro­benzoyl­hydrazono-κ(2) N,O)propionato(2−)-κO]oxidovanadium(V)
title_fullStr (4-Chloro­benzohydrazidato-κ(2) N′,O)[2-(4-chloro­benzoyl­hydrazono-κ(2) N,O)propionato(2−)-κO]oxidovanadium(V)
title_full_unstemmed (4-Chloro­benzohydrazidato-κ(2) N′,O)[2-(4-chloro­benzoyl­hydrazono-κ(2) N,O)propionato(2−)-κO]oxidovanadium(V)
title_short (4-Chloro­benzohydrazidato-κ(2) N′,O)[2-(4-chloro­benzoyl­hydrazono-κ(2) N,O)propionato(2−)-κO]oxidovanadium(V)
title_sort (4-chloro­benzohydrazidato-κ(2) n′,o)[2-(4-chloro­benzoyl­hydrazono-κ(2) n,o)propionato(2−)-κo]oxidovanadium(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969368/
https://www.ncbi.nlm.nih.gov/pubmed/21582662
http://dx.doi.org/10.1107/S1600536809019928
work_keys_str_mv AT wonghonwee 4chlorobenzohydrazidatok2no24chlorobenzoylhydrazonok2nopropionato2kooxidovanadiumv
AT lokongmun 4chlorobenzohydrazidatok2no24chlorobenzoylhydrazonok2nopropionato2kooxidovanadiumv
AT ngseikweng 4chlorobenzohydrazidatok2no24chlorobenzoylhydrazonok2nopropionato2kooxidovanadiumv

Ejemplares similares