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A one-dimensional cadmium(II) complex supported by a sulfur–nitrogen mixed-donor ligand
In the title compound, catena-poly[cadmium(II)-bis(μ-5-amino-1,3,4-thiadiazole-2-thiolato)-κ(2) N (3):S (2);κ(2) S (2):N (3)], [Cd(C(2)H(2)N(3)S(2))(2)](n), the Cd(II) ion is coordinated by two N atoms of the 1,3,4-thiadiazole rings from two ligands and two S atoms of sulfhydryl from two other...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969370/ https://www.ncbi.nlm.nih.gov/pubmed/21582754 http://dx.doi.org/10.1107/S160053680902371X |
| Sumario: | In the title compound, catena-poly[cadmium(II)-bis(μ-5-amino-1,3,4-thiadiazole-2-thiolato)-κ(2) N (3):S (2);κ(2) S (2):N (3)], [Cd(C(2)H(2)N(3)S(2))(2)](n), the Cd(II) ion is coordinated by two N atoms of the 1,3,4-thiadiazole rings from two ligands and two S atoms of sulfhydryl from two other ligands in a slightly distorted tetrahedral geometry. The ligands bridge Cd(II) ions, forming one-dimensional chains along [001], which are connected by N—H⋯N and N—H⋯S hydrogen bonds into a three-dimensional network. |
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