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A one-dimensional cadmium(II) complex supported by a sulfur–nitrogen mixed-donor ligand
In the title compound, catena-poly[cadmium(II)-bis(μ-5-amino-1,3,4-thiadiazole-2-thiolato)-κ(2) N (3):S (2);κ(2) S (2):N (3)], [Cd(C(2)H(2)N(3)S(2))(2)](n), the Cd(II) ion is coordinated by two N atoms of the 1,3,4-thiadiazole rings from two ligands and two S atoms of sulfhydryl from two other...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969370/ https://www.ncbi.nlm.nih.gov/pubmed/21582754 http://dx.doi.org/10.1107/S160053680902371X |
| _version_ | 1782190128800727040 |
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| author | Gao, Qian Zhang, Chao-Yan Cui, Yue Xie, Ya-Bo |
| author_facet | Gao, Qian Zhang, Chao-Yan Cui, Yue Xie, Ya-Bo |
| author_sort | Gao, Qian |
| collection | PubMed |
| description | In the title compound, catena-poly[cadmium(II)-bis(μ-5-amino-1,3,4-thiadiazole-2-thiolato)-κ(2) N (3):S (2);κ(2) S (2):N (3)], [Cd(C(2)H(2)N(3)S(2))(2)](n), the Cd(II) ion is coordinated by two N atoms of the 1,3,4-thiadiazole rings from two ligands and two S atoms of sulfhydryl from two other ligands in a slightly distorted tetrahedral geometry. The ligands bridge Cd(II) ions, forming one-dimensional chains along [001], which are connected by N—H⋯N and N—H⋯S hydrogen bonds into a three-dimensional network. |
| format | Text |
| id | pubmed-2969370 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29693702010-12-30 A one-dimensional cadmium(II) complex supported by a sulfur–nitrogen mixed-donor ligand Gao, Qian Zhang, Chao-Yan Cui, Yue Xie, Ya-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, catena-poly[cadmium(II)-bis(μ-5-amino-1,3,4-thiadiazole-2-thiolato)-κ(2) N (3):S (2);κ(2) S (2):N (3)], [Cd(C(2)H(2)N(3)S(2))(2)](n), the Cd(II) ion is coordinated by two N atoms of the 1,3,4-thiadiazole rings from two ligands and two S atoms of sulfhydryl from two other ligands in a slightly distorted tetrahedral geometry. The ligands bridge Cd(II) ions, forming one-dimensional chains along [001], which are connected by N—H⋯N and N—H⋯S hydrogen bonds into a three-dimensional network. International Union of Crystallography 2009-06-27 /pmc/articles/PMC2969370/ /pubmed/21582754 http://dx.doi.org/10.1107/S160053680902371X Text en © Gao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gao, Qian Zhang, Chao-Yan Cui, Yue Xie, Ya-Bo A one-dimensional cadmium(II) complex supported by a sulfur–nitrogen mixed-donor ligand |
| title | A one-dimensional cadmium(II) complex supported by a sulfur–nitrogen mixed-donor ligand |
| title_full | A one-dimensional cadmium(II) complex supported by a sulfur–nitrogen mixed-donor ligand |
| title_fullStr | A one-dimensional cadmium(II) complex supported by a sulfur–nitrogen mixed-donor ligand |
| title_full_unstemmed | A one-dimensional cadmium(II) complex supported by a sulfur–nitrogen mixed-donor ligand |
| title_short | A one-dimensional cadmium(II) complex supported by a sulfur–nitrogen mixed-donor ligand |
| title_sort | one-dimensional cadmium(ii) complex supported by a sulfur–nitrogen mixed-donor ligand |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969370/ https://www.ncbi.nlm.nih.gov/pubmed/21582754 http://dx.doi.org/10.1107/S160053680902371X |
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