Dibromidobis(1,10-phenanthroline-κ(2) N,N′)cadmium(II)

The title compound, [CdBr(2)(C(12)H(8)N(2))(2)], synthesized by the hydro­thermal reaction of Cd(CH(3)COO)(2)·2H(2)O with NaBr and 1,10-phenanthroline, has the Cd(II) cation coordinated by two Br(−) anions and four N atoms from two 1,10-phenanthroline ligands in a distorted octa­hedral geometry. The...

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Detalles Bibliográficos
Autores principales: Sun, Yu-Hui, Luo, Shu-Fen, Zhang, Xiu-Zhi, Du, Zi-Yi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969372/
https://www.ncbi.nlm.nih.gov/pubmed/21582654
http://dx.doi.org/10.1107/S1600536809020352
Descripción
Sumario:The title compound, [CdBr(2)(C(12)H(8)N(2))(2)], synthesized by the hydro­thermal reaction of Cd(CH(3)COO)(2)·2H(2)O with NaBr and 1,10-phenanthroline, has the Cd(II) cation coordinated by two Br(−) anions and four N atoms from two 1,10-phenanthroline ligands in a distorted octa­hedral geometry. The crystal packing is stabilized by inter­molecular π–π inter­actions with centroid–centroid distances 3.572 (1) and 3.671 (1) Å together with C—H⋯Br hydrogen bonds.

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