Cargando…
Dibromidobis(1,10-phenanthroline-κ(2) N,N′)cadmium(II)
The title compound, [CdBr(2)(C(12)H(8)N(2))(2)], synthesized by the hydrothermal reaction of Cd(CH(3)COO)(2)·2H(2)O with NaBr and 1,10-phenanthroline, has the Cd(II) cation coordinated by two Br(−) anions and four N atoms from two 1,10-phenanthroline ligands in a distorted octahedral geometry. The...
| Autores principales: | , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969372/ https://www.ncbi.nlm.nih.gov/pubmed/21582654 http://dx.doi.org/10.1107/S1600536809020352 |
| _version_ | 1782190129664753664 |
|---|---|
| author | Sun, Yu-Hui Luo, Shu-Fen Zhang, Xiu-Zhi Du, Zi-Yi |
| author_facet | Sun, Yu-Hui Luo, Shu-Fen Zhang, Xiu-Zhi Du, Zi-Yi |
| author_sort | Sun, Yu-Hui |
| collection | PubMed |
| description | The title compound, [CdBr(2)(C(12)H(8)N(2))(2)], synthesized by the hydrothermal reaction of Cd(CH(3)COO)(2)·2H(2)O with NaBr and 1,10-phenanthroline, has the Cd(II) cation coordinated by two Br(−) anions and four N atoms from two 1,10-phenanthroline ligands in a distorted octahedral geometry. The crystal packing is stabilized by intermolecular π–π interactions with centroid–centroid distances 3.572 (1) and 3.671 (1) Å together with C—H⋯Br hydrogen bonds. |
| format | Text |
| id | pubmed-2969372 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29693722010-12-30 Dibromidobis(1,10-phenanthroline-κ(2) N,N′)cadmium(II) Sun, Yu-Hui Luo, Shu-Fen Zhang, Xiu-Zhi Du, Zi-Yi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [CdBr(2)(C(12)H(8)N(2))(2)], synthesized by the hydrothermal reaction of Cd(CH(3)COO)(2)·2H(2)O with NaBr and 1,10-phenanthroline, has the Cd(II) cation coordinated by two Br(−) anions and four N atoms from two 1,10-phenanthroline ligands in a distorted octahedral geometry. The crystal packing is stabilized by intermolecular π–π interactions with centroid–centroid distances 3.572 (1) and 3.671 (1) Å together with C—H⋯Br hydrogen bonds. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969372/ /pubmed/21582654 http://dx.doi.org/10.1107/S1600536809020352 Text en © Sun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Sun, Yu-Hui Luo, Shu-Fen Zhang, Xiu-Zhi Du, Zi-Yi Dibromidobis(1,10-phenanthroline-κ(2) N,N′)cadmium(II) |
| title | Dibromidobis(1,10-phenanthroline-κ(2)
N,N′)cadmium(II) |
| title_full | Dibromidobis(1,10-phenanthroline-κ(2)
N,N′)cadmium(II) |
| title_fullStr | Dibromidobis(1,10-phenanthroline-κ(2)
N,N′)cadmium(II) |
| title_full_unstemmed | Dibromidobis(1,10-phenanthroline-κ(2)
N,N′)cadmium(II) |
| title_short | Dibromidobis(1,10-phenanthroline-κ(2)
N,N′)cadmium(II) |
| title_sort | dibromidobis(1,10-phenanthroline-κ(2)
n,n′)cadmium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969372/ https://www.ncbi.nlm.nih.gov/pubmed/21582654 http://dx.doi.org/10.1107/S1600536809020352 |
| work_keys_str_mv | AT sunyuhui dibromidobis110phenanthrolinek2nncadmiumii AT luoshufen dibromidobis110phenanthrolinek2nncadmiumii AT zhangxiuzhi dibromidobis110phenanthrolinek2nncadmiumii AT duziyi dibromidobis110phenanthrolinek2nncadmiumii |