Bis(μ-2-methyl­quinolin-1-ium-8-olato-κ(2) O:O′)bis­[(2-methyl­quinolin-1-ium-8-olato-κO)tris­(nitrato-κ(2) O,O′)lanthanum(III)]

The two independent N-heterocycles in the centrosymmetric title compound, [La(2)(C(10)H(9)NO)(4)(NO(3))(6)], exist in the zwitterionic form. One of these binds to one metal center, whereas the other bridges two metal centers. The La atom is chelated by three nitrate groups and is surrounded by nine...

Descripción completa

Detalles Bibliográficos
Autores principales: Fazaeli, Yousef, Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969373/
https://www.ncbi.nlm.nih.gov/pubmed/21582656
http://dx.doi.org/10.1107/S1600536809019746
Descripción
Sumario:The two independent N-heterocycles in the centrosymmetric title compound, [La(2)(C(10)H(9)NO)(4)(NO(3))(6)], exist in the zwitterionic form. One of these binds to one metal center, whereas the other bridges two metal centers. The La atom is chelated by three nitrate groups and is surrounded by nine O atoms in a coordination environment based on a distorted monocapped square-anti­prism. The dinuclear structure is further stabilized by intra­molecular N—H⋯O(nitrate) hydrogen bonds.

Ejemplares similares