Bis(μ-2-methyl­quinolin-1-ium-8-olato-κ(2) O:O′)bis­[(2-methyl­quinolin-1-ium-8-olato-κO)tris­(nitrato-κ(2) O,O′)lanthanum(III)]

The two independent N-heterocycles in the centrosymmetric title compound, [La(2)(C(10)H(9)NO)(4)(NO(3))(6)], exist in the zwitterionic form. One of these binds to one metal center, whereas the other bridges two metal centers. The La atom is chelated by three nitrate groups and is surrounded by nine...

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Detalles Bibliográficos
Autores principales: Fazaeli, Yousef, Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969373/
https://www.ncbi.nlm.nih.gov/pubmed/21582656
http://dx.doi.org/10.1107/S1600536809019746
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author Fazaeli, Yousef
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_facet Fazaeli, Yousef
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_sort Fazaeli, Yousef
collection PubMed
description The two independent N-heterocycles in the centrosymmetric title compound, [La(2)(C(10)H(9)NO)(4)(NO(3))(6)], exist in the zwitterionic form. One of these binds to one metal center, whereas the other bridges two metal centers. The La atom is chelated by three nitrate groups and is surrounded by nine O atoms in a coordination environment based on a distorted monocapped square-anti­prism. The dinuclear structure is further stabilized by intra­molecular N—H⋯O(nitrate) hydrogen bonds.
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spelling pubmed-29693732010-12-30 Bis(μ-2-methyl­quinolin-1-ium-8-olato-κ(2) O:O′)bis­[(2-methyl­quinolin-1-ium-8-olato-κO)tris­(nitrato-κ(2) O,O′)lanthanum(III)] Fazaeli, Yousef Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The two independent N-heterocycles in the centrosymmetric title compound, [La(2)(C(10)H(9)NO)(4)(NO(3))(6)], exist in the zwitterionic form. One of these binds to one metal center, whereas the other bridges two metal centers. The La atom is chelated by three nitrate groups and is surrounded by nine O atoms in a coordination environment based on a distorted monocapped square-anti­prism. The dinuclear structure is further stabilized by intra­molecular N—H⋯O(nitrate) hydrogen bonds. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969373/ /pubmed/21582656 http://dx.doi.org/10.1107/S1600536809019746 Text en © Fazaeli et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fazaeli, Yousef
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
Bis(μ-2-methyl­quinolin-1-ium-8-olato-κ(2) O:O′)bis­[(2-methyl­quinolin-1-ium-8-olato-κO)tris­(nitrato-κ(2) O,O′)lanthanum(III)]
title Bis(μ-2-methyl­quinolin-1-ium-8-olato-κ(2) O:O′)bis­[(2-methyl­quinolin-1-ium-8-olato-κO)tris­(nitrato-κ(2) O,O′)lanthanum(III)]
title_full Bis(μ-2-methyl­quinolin-1-ium-8-olato-κ(2) O:O′)bis­[(2-methyl­quinolin-1-ium-8-olato-κO)tris­(nitrato-κ(2) O,O′)lanthanum(III)]
title_fullStr Bis(μ-2-methyl­quinolin-1-ium-8-olato-κ(2) O:O′)bis­[(2-methyl­quinolin-1-ium-8-olato-κO)tris­(nitrato-κ(2) O,O′)lanthanum(III)]
title_full_unstemmed Bis(μ-2-methyl­quinolin-1-ium-8-olato-κ(2) O:O′)bis­[(2-methyl­quinolin-1-ium-8-olato-κO)tris­(nitrato-κ(2) O,O′)lanthanum(III)]
title_short Bis(μ-2-methyl­quinolin-1-ium-8-olato-κ(2) O:O′)bis­[(2-methyl­quinolin-1-ium-8-olato-κO)tris­(nitrato-κ(2) O,O′)lanthanum(III)]
title_sort bis(μ-2-methyl­quinolin-1-ium-8-olato-κ(2) o:o′)bis­[(2-methyl­quinolin-1-ium-8-olato-κo)tris­(nitrato-κ(2) o,o′)lanthanum(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969373/
https://www.ncbi.nlm.nih.gov/pubmed/21582656
http://dx.doi.org/10.1107/S1600536809019746
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