Poly[diaqua­(μ(4)-3,5-dicarb­oxyl­ato­pyra­zol-1-ido-κ(6) N (1),O (5):N (2),O (3):O (3′):O (5),O (5′))lanthanum(III)]

In the title coordination polymer, [La(C(5)HN(2)O(4))(H(2)O)(2)](n), the lanthanum(III) metal centre is nine-coordinated, with a distorted tricapped trigonal prismatic geometry, by the O atoms of two water mol­ecules and by two N and five O atoms of two N,O-bidentate, one O,O′-bidentate and one O-mo...

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Detalles Bibliográficos
Autores principales: Xia, Jun, Wei, Jun-Fu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969374/
https://www.ncbi.nlm.nih.gov/pubmed/21582674
http://dx.doi.org/10.1107/S1600536809020479
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author Xia, Jun
Wei, Jun-Fu
author_facet Xia, Jun
Wei, Jun-Fu
author_sort Xia, Jun
collection PubMed
description In the title coordination polymer, [La(C(5)HN(2)O(4))(H(2)O)(2)](n), the lanthanum(III) metal centre is nine-coordinated, with a distorted tricapped trigonal prismatic geometry, by the O atoms of two water mol­ecules and by two N and five O atoms of two N,O-bidentate, one O,O′-bidentate and one O-mono­dentate 3,5-dicarb­oxyl­ato­pyra­zol-1-ide ligands. The polymeric three-dimensional structure is stabilized by inter­molecular O—H⋯O hydrogen bonds.
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spelling pubmed-29693742010-12-30 Poly[diaqua­(μ(4)-3,5-dicarb­oxyl­ato­pyra­zol-1-ido-κ(6) N (1),O (5):N (2),O (3):O (3′):O (5),O (5′))lanthanum(III)] Xia, Jun Wei, Jun-Fu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [La(C(5)HN(2)O(4))(H(2)O)(2)](n), the lanthanum(III) metal centre is nine-coordinated, with a distorted tricapped trigonal prismatic geometry, by the O atoms of two water mol­ecules and by two N and five O atoms of two N,O-bidentate, one O,O′-bidentate and one O-mono­dentate 3,5-dicarb­oxyl­ato­pyra­zol-1-ide ligands. The polymeric three-dimensional structure is stabilized by inter­molecular O—H⋯O hydrogen bonds. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969374/ /pubmed/21582674 http://dx.doi.org/10.1107/S1600536809020479 Text en © Xia and Wei 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xia, Jun
Wei, Jun-Fu
Poly[diaqua­(μ(4)-3,5-dicarb­oxyl­ato­pyra­zol-1-ido-κ(6) N (1),O (5):N (2),O (3):O (3′):O (5),O (5′))lanthanum(III)]
title Poly[diaqua­(μ(4)-3,5-dicarb­oxyl­ato­pyra­zol-1-ido-κ(6) N (1),O (5):N (2),O (3):O (3′):O (5),O (5′))lanthanum(III)]
title_full Poly[diaqua­(μ(4)-3,5-dicarb­oxyl­ato­pyra­zol-1-ido-κ(6) N (1),O (5):N (2),O (3):O (3′):O (5),O (5′))lanthanum(III)]
title_fullStr Poly[diaqua­(μ(4)-3,5-dicarb­oxyl­ato­pyra­zol-1-ido-κ(6) N (1),O (5):N (2),O (3):O (3′):O (5),O (5′))lanthanum(III)]
title_full_unstemmed Poly[diaqua­(μ(4)-3,5-dicarb­oxyl­ato­pyra­zol-1-ido-κ(6) N (1),O (5):N (2),O (3):O (3′):O (5),O (5′))lanthanum(III)]
title_short Poly[diaqua­(μ(4)-3,5-dicarb­oxyl­ato­pyra­zol-1-ido-κ(6) N (1),O (5):N (2),O (3):O (3′):O (5),O (5′))lanthanum(III)]
title_sort poly[diaqua­(μ(4)-3,5-dicarb­oxyl­ato­pyra­zol-1-ido-κ(6) n (1),o (5):n (2),o (3):o (3′):o (5),o (5′))lanthanum(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969374/
https://www.ncbi.nlm.nih.gov/pubmed/21582674
http://dx.doi.org/10.1107/S1600536809020479
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