Cargando…
trans-Bis(acetonitrile-κN)bis{1,2-bis[bis(3-hydroxypropyl)phosphino]ethane-κ(2) P,P′}iron(II) dichloride
In the title compound, [Fe(CH(3)CN)(2)(C(14)H(32)O(4)P(2))(2)]Cl(2), the Fe(II) atom lies on a crystallographic inversion center and has a distorted trans-FeN(2)P(4) octahedral coordination environment arising from two P,P′-bidentate 1,2-bis[bis(3-hydroxypropyl)phosphino]ethane ligands in the e...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969375/ https://www.ncbi.nlm.nih.gov/pubmed/21582706 http://dx.doi.org/10.1107/S1600536809021758 |
Sumario: | In the title compound, [Fe(CH(3)CN)(2)(C(14)H(32)O(4)P(2))(2)]Cl(2), the Fe(II) atom lies on a crystallographic inversion center and has a distorted trans-FeN(2)P(4) octahedral coordination environment arising from two P,P′-bidentate 1,2-bis[bis(3-hydroxypropyl)phosphino]ethane ligands in the equatorial plane and two acetonitrile molecules in the axial positions. One of the pendant –(CH(2))(3)OH groups of the ligand is disordered over two sets of sites in a 0.597 (5):0.403 (5) ratio. In the crystal, O—H⋯Cl and O—H⋯O hydrogen bonding helps to establish the packing. |
---|