trans-Bis(acetonitrile-κN)bis­{1,2-bis­[bis­(3-hydroxy­prop­yl)phosphino]ethane-κ(2) P,P′}iron(II) dichloride

In the title compound, [Fe(CH(3)CN)(2)(C(14)H(32)O(4)P(2))(2)]Cl(2), the Fe(II) atom lies on a crystallographic inversion center and has a distorted trans-FeN(2)P(4) octa­hedral coordination environment arising from two P,P′-bidentate 1,2-bis­[bis­(3-hydroxy­prop­yl)phosphino]ethane ligands in the e...

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Detalles Bibliográficos
Autores principales: Gohdes, J. W., Zakharov, Lev N., Tyler, David R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969375/
https://www.ncbi.nlm.nih.gov/pubmed/21582706
http://dx.doi.org/10.1107/S1600536809021758
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author Gohdes, J. W.
Zakharov, Lev N.
Tyler, David R.
author_facet Gohdes, J. W.
Zakharov, Lev N.
Tyler, David R.
author_sort Gohdes, J. W.
collection PubMed
description In the title compound, [Fe(CH(3)CN)(2)(C(14)H(32)O(4)P(2))(2)]Cl(2), the Fe(II) atom lies on a crystallographic inversion center and has a distorted trans-FeN(2)P(4) octa­hedral coordination environment arising from two P,P′-bidentate 1,2-bis­[bis­(3-hydroxy­prop­yl)phosphino]ethane ligands in the equatorial plane and two acetonitrile mol­ecules in the axial positions. One of the pendant –(CH(2))(3)OH groups of the ligand is disordered over two sets of sites in a 0.597 (5):0.403 (5) ratio. In the crystal, O—H⋯Cl and O—H⋯O hydrogen bonding helps to establish the packing.
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spelling pubmed-29693752010-12-30 trans-Bis(acetonitrile-κN)bis­{1,2-bis­[bis­(3-hydroxy­prop­yl)phosphino]ethane-κ(2) P,P′}iron(II) dichloride Gohdes, J. W. Zakharov, Lev N. Tyler, David R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(CH(3)CN)(2)(C(14)H(32)O(4)P(2))(2)]Cl(2), the Fe(II) atom lies on a crystallographic inversion center and has a distorted trans-FeN(2)P(4) octa­hedral coordination environment arising from two P,P′-bidentate 1,2-bis­[bis­(3-hydroxy­prop­yl)phosphino]ethane ligands in the equatorial plane and two acetonitrile mol­ecules in the axial positions. One of the pendant –(CH(2))(3)OH groups of the ligand is disordered over two sets of sites in a 0.597 (5):0.403 (5) ratio. In the crystal, O—H⋯Cl and O—H⋯O hydrogen bonding helps to establish the packing. International Union of Crystallography 2009-06-17 /pmc/articles/PMC2969375/ /pubmed/21582706 http://dx.doi.org/10.1107/S1600536809021758 Text en © Gohdes et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gohdes, J. W.
Zakharov, Lev N.
Tyler, David R.
trans-Bis(acetonitrile-κN)bis­{1,2-bis­[bis­(3-hydroxy­prop­yl)phosphino]ethane-κ(2) P,P′}iron(II) dichloride
title trans-Bis(acetonitrile-κN)bis­{1,2-bis­[bis­(3-hydroxy­prop­yl)phosphino]ethane-κ(2) P,P′}iron(II) dichloride
title_full trans-Bis(acetonitrile-κN)bis­{1,2-bis­[bis­(3-hydroxy­prop­yl)phosphino]ethane-κ(2) P,P′}iron(II) dichloride
title_fullStr trans-Bis(acetonitrile-κN)bis­{1,2-bis­[bis­(3-hydroxy­prop­yl)phosphino]ethane-κ(2) P,P′}iron(II) dichloride
title_full_unstemmed trans-Bis(acetonitrile-κN)bis­{1,2-bis­[bis­(3-hydroxy­prop­yl)phosphino]ethane-κ(2) P,P′}iron(II) dichloride
title_short trans-Bis(acetonitrile-κN)bis­{1,2-bis­[bis­(3-hydroxy­prop­yl)phosphino]ethane-κ(2) P,P′}iron(II) dichloride
title_sort trans-bis(acetonitrile-κn)bis­{1,2-bis­[bis­(3-hydroxy­prop­yl)phosphino]ethane-κ(2) p,p′}iron(ii) dichloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969375/
https://www.ncbi.nlm.nih.gov/pubmed/21582706
http://dx.doi.org/10.1107/S1600536809021758
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AT zakharovlevn transbisacetonitrileknbis12bisbis3hydroxypropylphosphinoethanek2ppironiidichloride
AT tylerdavidr transbisacetonitrileknbis12bisbis3hydroxypropylphosphinoethanek2ppironiidichloride

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