N-[2-(2-Chloro­phen­yl)-2-hydroxy­ethyl]propan-2-aminium hemioxalate

The asymmetric unit of the title compound, C(11)H(17)ClNO(+)·0.5C(2)O(4) (2−), consists of one N-[2-(2-chloro­phen­yl)-2-hydroxy­ethyl]propan-2-ammonium cation and one-half of a centrosymmetric oxalate anion. In the cation, the C/C/N plane of the ethyl­ammonium group is almost perpendicular to the b...

Descripción completa

Detalles Bibliográficos
Autores principales: Tang, Zhan, Xu, Min, Zhang, Hui-Cheng, Feng, Hai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969379/
https://www.ncbi.nlm.nih.gov/pubmed/21582930
http://dx.doi.org/10.1107/S1600536809022740
_version_ 1782190132051312640
author Tang, Zhan
Xu, Min
Zhang, Hui-Cheng
Feng, Hai
author_facet Tang, Zhan
Xu, Min
Zhang, Hui-Cheng
Feng, Hai
author_sort Tang, Zhan
collection PubMed
description The asymmetric unit of the title compound, C(11)H(17)ClNO(+)·0.5C(2)O(4) (2−), consists of one N-[2-(2-chloro­phen­yl)-2-hydroxy­ethyl]propan-2-ammonium cation and one-half of a centrosymmetric oxalate anion. In the cation, the C/C/N plane of the ethyl­ammonium group is almost perpendicular to the benzene ring, with a dihedral angle of 88.72 (17)°. In the crystal structure, the two components are connected by O—H⋯O and N—H⋯O hydrogen bonds, forming a supra­molecular tape along the a axis. Between the tapes, a C—H⋯O inter­action is observed.
format Text
id pubmed-2969379
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29693792010-12-30 N-[2-(2-Chloro­phen­yl)-2-hydroxy­ethyl]propan-2-aminium hemioxalate Tang, Zhan Xu, Min Zhang, Hui-Cheng Feng, Hai Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(11)H(17)ClNO(+)·0.5C(2)O(4) (2−), consists of one N-[2-(2-chloro­phen­yl)-2-hydroxy­ethyl]propan-2-ammonium cation and one-half of a centrosymmetric oxalate anion. In the cation, the C/C/N plane of the ethyl­ammonium group is almost perpendicular to the benzene ring, with a dihedral angle of 88.72 (17)°. In the crystal structure, the two components are connected by O—H⋯O and N—H⋯O hydrogen bonds, forming a supra­molecular tape along the a axis. Between the tapes, a C—H⋯O inter­action is observed. International Union of Crystallography 2009-06-24 /pmc/articles/PMC2969379/ /pubmed/21582930 http://dx.doi.org/10.1107/S1600536809022740 Text en © Tang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tang, Zhan
Xu, Min
Zhang, Hui-Cheng
Feng, Hai
N-[2-(2-Chloro­phen­yl)-2-hydroxy­ethyl]propan-2-aminium hemioxalate
title N-[2-(2-Chloro­phen­yl)-2-hydroxy­ethyl]propan-2-aminium hemioxalate
title_full N-[2-(2-Chloro­phen­yl)-2-hydroxy­ethyl]propan-2-aminium hemioxalate
title_fullStr N-[2-(2-Chloro­phen­yl)-2-hydroxy­ethyl]propan-2-aminium hemioxalate
title_full_unstemmed N-[2-(2-Chloro­phen­yl)-2-hydroxy­ethyl]propan-2-aminium hemioxalate
title_short N-[2-(2-Chloro­phen­yl)-2-hydroxy­ethyl]propan-2-aminium hemioxalate
title_sort n-[2-(2-chloro­phen­yl)-2-hydroxy­ethyl]propan-2-aminium hemioxalate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969379/
https://www.ncbi.nlm.nih.gov/pubmed/21582930
http://dx.doi.org/10.1107/S1600536809022740
work_keys_str_mv AT tangzhan n22chlorophenyl2hydroxyethylpropan2aminiumhemioxalate
AT xumin n22chlorophenyl2hydroxyethylpropan2aminiumhemioxalate
AT zhanghuicheng n22chlorophenyl2hydroxyethylpropan2aminiumhemioxalate
AT fenghai n22chlorophenyl2hydroxyethylpropan2aminiumhemioxalate

Ejemplares similares