Dichlorido[1-(8-quinolylimino­meth­yl)-2-naphtholato]iron(III)

The Fe(III) ion in the title complex, [FeCl(2)(C(20)H(13)N(2)O)], has a distorted square-pyramidal coordination formed by one O atom and two N atoms from a tridentate 1-(8-quinolylimino­meth­yl)-2-naphtholate ligand and two Cl atoms. In the crystal structure, mol­ecules form a column structure along...

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Detalles Bibliográficos
Autores principales: Urakami, Daisuke, Inoue, Katsuya, Hayami, Shinya
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969382/
https://www.ncbi.nlm.nih.gov/pubmed/21582725
http://dx.doi.org/10.1107/S1600536809022880
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author Urakami, Daisuke
Inoue, Katsuya
Hayami, Shinya
author_facet Urakami, Daisuke
Inoue, Katsuya
Hayami, Shinya
author_sort Urakami, Daisuke
collection PubMed
description The Fe(III) ion in the title complex, [FeCl(2)(C(20)H(13)N(2)O)], has a distorted square-pyramidal coordination formed by one O atom and two N atoms from a tridentate 1-(8-quinolylimino­meth­yl)-2-naphtholate ligand and two Cl atoms. In the crystal structure, mol­ecules form a column structure along the a axis through π–π stacking inter­actions, with centroid–centroid distances of 3.657 (1) and 3.818 (2) Å. Weak C—H⋯Cl inter­actions are observed between the columns.
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spelling pubmed-29693822010-12-30 Dichlorido[1-(8-quinolylimino­meth­yl)-2-naphtholato]iron(III) Urakami, Daisuke Inoue, Katsuya Hayami, Shinya Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Fe(III) ion in the title complex, [FeCl(2)(C(20)H(13)N(2)O)], has a distorted square-pyramidal coordination formed by one O atom and two N atoms from a tridentate 1-(8-quinolylimino­meth­yl)-2-naphtholate ligand and two Cl atoms. In the crystal structure, mol­ecules form a column structure along the a axis through π–π stacking inter­actions, with centroid–centroid distances of 3.657 (1) and 3.818 (2) Å. Weak C—H⋯Cl inter­actions are observed between the columns. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969382/ /pubmed/21582725 http://dx.doi.org/10.1107/S1600536809022880 Text en © Urakami et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Urakami, Daisuke
Inoue, Katsuya
Hayami, Shinya
Dichlorido[1-(8-quinolylimino­meth­yl)-2-naphtholato]iron(III)
title Dichlorido[1-(8-quinolylimino­meth­yl)-2-naphtholato]iron(III)
title_full Dichlorido[1-(8-quinolylimino­meth­yl)-2-naphtholato]iron(III)
title_fullStr Dichlorido[1-(8-quinolylimino­meth­yl)-2-naphtholato]iron(III)
title_full_unstemmed Dichlorido[1-(8-quinolylimino­meth­yl)-2-naphtholato]iron(III)
title_short Dichlorido[1-(8-quinolylimino­meth­yl)-2-naphtholato]iron(III)
title_sort dichlorido[1-(8-quinolylimino­meth­yl)-2-naphtholato]iron(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969382/
https://www.ncbi.nlm.nih.gov/pubmed/21582725
http://dx.doi.org/10.1107/S1600536809022880
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AT inouekatsuya dichlorido18quinolyliminomethyl2naphtholatoironiii
AT hayamishinya dichlorido18quinolyliminomethyl2naphtholatoironiii

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