Bis(3,5-dimethyl­pyridine-κN)bis­(tri-tert-butoxy­silanethiol­ato-κS)chromium(II) toluene solvate

In the title chromium silanethiol­ate, [Cr(C(12)H(27)O(3)SSi)(2)(C(7)H(9)N)(2)]·C(7)H(8), the Cr(II) atom is coordinated by two S and two N atoms in a distorted square-planar geometrical arrangement. The mononuclear mol­ecule lies on a twofold axis that passes through the pyridine N atoms. The tolue...

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Detalles Bibliográficos
Autores principales: Ciborska, Anna, Baranowska, Katarzyna, Wojnowski, Wiesław
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969383/
https://www.ncbi.nlm.nih.gov/pubmed/21582696
http://dx.doi.org/10.1107/S1600536809021680
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author Ciborska, Anna
Baranowska, Katarzyna
Wojnowski, Wiesław
author_facet Ciborska, Anna
Baranowska, Katarzyna
Wojnowski, Wiesław
author_sort Ciborska, Anna
collection PubMed
description In the title chromium silanethiol­ate, [Cr(C(12)H(27)O(3)SSi)(2)(C(7)H(9)N)(2)]·C(7)H(8), the Cr(II) atom is coordinated by two S and two N atoms in a distorted square-planar geometrical arrangement. The mononuclear mol­ecule lies on a twofold axis that passes through the pyridine N atoms. The toluene solvent mol­ecule is equally disordered about a twofold axis.
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spelling pubmed-29693832010-12-30 Bis(3,5-dimethyl­pyridine-κN)bis­(tri-tert-butoxy­silanethiol­ato-κS)chromium(II) toluene solvate Ciborska, Anna Baranowska, Katarzyna Wojnowski, Wiesław Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title chromium silanethiol­ate, [Cr(C(12)H(27)O(3)SSi)(2)(C(7)H(9)N)(2)]·C(7)H(8), the Cr(II) atom is coordinated by two S and two N atoms in a distorted square-planar geometrical arrangement. The mononuclear mol­ecule lies on a twofold axis that passes through the pyridine N atoms. The toluene solvent mol­ecule is equally disordered about a twofold axis. International Union of Crystallography 2009-06-13 /pmc/articles/PMC2969383/ /pubmed/21582696 http://dx.doi.org/10.1107/S1600536809021680 Text en © Ciborska et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ciborska, Anna
Baranowska, Katarzyna
Wojnowski, Wiesław
Bis(3,5-dimethyl­pyridine-κN)bis­(tri-tert-butoxy­silanethiol­ato-κS)chromium(II) toluene solvate
title Bis(3,5-dimethyl­pyridine-κN)bis­(tri-tert-butoxy­silanethiol­ato-κS)chromium(II) toluene solvate
title_full Bis(3,5-dimethyl­pyridine-κN)bis­(tri-tert-butoxy­silanethiol­ato-κS)chromium(II) toluene solvate
title_fullStr Bis(3,5-dimethyl­pyridine-κN)bis­(tri-tert-butoxy­silanethiol­ato-κS)chromium(II) toluene solvate
title_full_unstemmed Bis(3,5-dimethyl­pyridine-κN)bis­(tri-tert-butoxy­silanethiol­ato-κS)chromium(II) toluene solvate
title_short Bis(3,5-dimethyl­pyridine-κN)bis­(tri-tert-butoxy­silanethiol­ato-κS)chromium(II) toluene solvate
title_sort bis(3,5-dimethyl­pyridine-κn)bis­(tri-tert-butoxy­silanethiol­ato-κs)chromium(ii) toluene solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969383/
https://www.ncbi.nlm.nih.gov/pubmed/21582696
http://dx.doi.org/10.1107/S1600536809021680
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AT baranowskakatarzyna bis35dimethylpyridineknbistritertbutoxysilanethiolatokschromiumiitoluenesolvate
AT wojnowskiwiesław bis35dimethylpyridineknbistritertbutoxysilanethiolatokschromiumiitoluenesolvate

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