Tetraphenyl­arsonium cis-bis­[1,2-bis­(tri­fluoro­meth­yl)ethene-1,2-dithiol­ato]platinate(II)

In the title compound, (C(24)H(20)As)[Pt(C(4)F(6)S(2))(2)], the cation lies on a twofold rotation axis while the anion has crystallographic inversion symmetry. The Pt(II) ion is in a slightly distorted square-planar coordination environment. The F atoms of both unique –CF(3) groups are disordered ov...

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Detalles Bibliográficos
Autores principales: Hosking, Stephanie, Lough, Alan J., Fekl, Ulrich
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969384/
https://www.ncbi.nlm.nih.gov/pubmed/21582694
http://dx.doi.org/10.1107/S1600536809021527
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author Hosking, Stephanie
Lough, Alan J.
Fekl, Ulrich
author_facet Hosking, Stephanie
Lough, Alan J.
Fekl, Ulrich
author_sort Hosking, Stephanie
collection PubMed
description In the title compound, (C(24)H(20)As)[Pt(C(4)F(6)S(2))(2)], the cation lies on a twofold rotation axis while the anion has crystallographic inversion symmetry. The Pt(II) ion is in a slightly distorted square-planar coordination environment. The F atoms of both unique –CF(3) groups are disordered over two sets of sites, the ratios of refined occupancies being 0.677 (15):0.323 (15) and 0.640 (16):0.360 (16). The crystal structure is the first to date of a monoanionic [Pt(tfd)(2)](−) species [tfd is 1,2-bis­(trifluoro­meth­yl)ethene-1,2-dithiol­ate] with a non-redox-active cation.
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spelling pubmed-29693842010-12-30 Tetraphenyl­arsonium cis-bis­[1,2-bis­(tri­fluoro­meth­yl)ethene-1,2-dithiol­ato]platinate(II) Hosking, Stephanie Lough, Alan J. Fekl, Ulrich Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(24)H(20)As)[Pt(C(4)F(6)S(2))(2)], the cation lies on a twofold rotation axis while the anion has crystallographic inversion symmetry. The Pt(II) ion is in a slightly distorted square-planar coordination environment. The F atoms of both unique –CF(3) groups are disordered over two sets of sites, the ratios of refined occupancies being 0.677 (15):0.323 (15) and 0.640 (16):0.360 (16). The crystal structure is the first to date of a monoanionic [Pt(tfd)(2)](−) species [tfd is 1,2-bis­(trifluoro­meth­yl)ethene-1,2-dithiol­ate] with a non-redox-active cation. International Union of Crystallography 2009-06-13 /pmc/articles/PMC2969384/ /pubmed/21582694 http://dx.doi.org/10.1107/S1600536809021527 Text en © Hosking et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hosking, Stephanie
Lough, Alan J.
Fekl, Ulrich
Tetraphenyl­arsonium cis-bis­[1,2-bis­(tri­fluoro­meth­yl)ethene-1,2-dithiol­ato]platinate(II)
title Tetraphenyl­arsonium cis-bis­[1,2-bis­(tri­fluoro­meth­yl)ethene-1,2-dithiol­ato]platinate(II)
title_full Tetraphenyl­arsonium cis-bis­[1,2-bis­(tri­fluoro­meth­yl)ethene-1,2-dithiol­ato]platinate(II)
title_fullStr Tetraphenyl­arsonium cis-bis­[1,2-bis­(tri­fluoro­meth­yl)ethene-1,2-dithiol­ato]platinate(II)
title_full_unstemmed Tetraphenyl­arsonium cis-bis­[1,2-bis­(tri­fluoro­meth­yl)ethene-1,2-dithiol­ato]platinate(II)
title_short Tetraphenyl­arsonium cis-bis­[1,2-bis­(tri­fluoro­meth­yl)ethene-1,2-dithiol­ato]platinate(II)
title_sort tetraphenyl­arsonium cis-bis­[1,2-bis­(tri­fluoro­meth­yl)ethene-1,2-dithiol­ato]platinate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969384/
https://www.ncbi.nlm.nih.gov/pubmed/21582694
http://dx.doi.org/10.1107/S1600536809021527
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AT loughalanj tetraphenylarsoniumcisbis12bistrifluoromethylethene12dithiolatoplatinateii
AT feklulrich tetraphenylarsoniumcisbis12bistrifluoromethylethene12dithiolatoplatinateii

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