4-Bromo­seleno­anisole

The title compound, 1-bromo-4-methyl­seleno­benzene, C(7)H(7)BrSe, was prepared by methyl­ation of 4-bromo­seleno­phenolate with methyl iodide, and crystals suitable for structure determination were obtained by sublimation. The mol­ecule is essentially planar; the Se—Me bond is rotated by only 2.59 ...

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Detalles Bibliográficos
Autores principales: Sørensen, Henning Osholm, Stuhr-Hansen, Nicolai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969389/
https://www.ncbi.nlm.nih.gov/pubmed/21582926
http://dx.doi.org/10.1107/S160053680902296X
Descripción
Sumario:The title compound, 1-bromo-4-methyl­seleno­benzene, C(7)H(7)BrSe, was prepared by methyl­ation of 4-bromo­seleno­phenolate with methyl iodide, and crystals suitable for structure determination were obtained by sublimation. The mol­ecule is essentially planar; the Se—Me bond is rotated by only 2.59 (19)° out of the least-squares plane of the benzene ring. The most pronounced intermolecular interactions are two hydrogen bonds of the type C—H⋯π, which determine a herring-bone pattern in the crystal packing.

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