4-Bromo­seleno­anisole

The title compound, 1-bromo-4-methyl­seleno­benzene, C(7)H(7)BrSe, was prepared by methyl­ation of 4-bromo­seleno­phenolate with methyl iodide, and crystals suitable for structure determination were obtained by sublimation. The mol­ecule is essentially planar; the Se—Me bond is rotated by only 2.59 ...

Descripción completa

Detalles Bibliográficos
Autores principales: Sørensen, Henning Osholm, Stuhr-Hansen, Nicolai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969389/
https://www.ncbi.nlm.nih.gov/pubmed/21582926
http://dx.doi.org/10.1107/S160053680902296X
_version_ 1782190135623811072
author Sørensen, Henning Osholm
Stuhr-Hansen, Nicolai
author_facet Sørensen, Henning Osholm
Stuhr-Hansen, Nicolai
author_sort Sørensen, Henning Osholm
collection PubMed
description The title compound, 1-bromo-4-methyl­seleno­benzene, C(7)H(7)BrSe, was prepared by methyl­ation of 4-bromo­seleno­phenolate with methyl iodide, and crystals suitable for structure determination were obtained by sublimation. The mol­ecule is essentially planar; the Se—Me bond is rotated by only 2.59 (19)° out of the least-squares plane of the benzene ring. The most pronounced intermolecular interactions are two hydrogen bonds of the type C—H⋯π, which determine a herring-bone pattern in the crystal packing.
format Text
id pubmed-2969389
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29693892010-12-30 4-Bromo­seleno­anisole Sørensen, Henning Osholm Stuhr-Hansen, Nicolai Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, 1-bromo-4-methyl­seleno­benzene, C(7)H(7)BrSe, was prepared by methyl­ation of 4-bromo­seleno­phenolate with methyl iodide, and crystals suitable for structure determination were obtained by sublimation. The mol­ecule is essentially planar; the Se—Me bond is rotated by only 2.59 (19)° out of the least-squares plane of the benzene ring. The most pronounced intermolecular interactions are two hydrogen bonds of the type C—H⋯π, which determine a herring-bone pattern in the crystal packing. International Union of Crystallography 2009-06-24 /pmc/articles/PMC2969389/ /pubmed/21582926 http://dx.doi.org/10.1107/S160053680902296X Text en © Sørensen and Stuhr-Hansen 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sørensen, Henning Osholm
Stuhr-Hansen, Nicolai
4-Bromo­seleno­anisole
title 4-Bromo­seleno­anisole
title_full 4-Bromo­seleno­anisole
title_fullStr 4-Bromo­seleno­anisole
title_full_unstemmed 4-Bromo­seleno­anisole
title_short 4-Bromo­seleno­anisole
title_sort 4-bromo­seleno­anisole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969389/
https://www.ncbi.nlm.nih.gov/pubmed/21582926
http://dx.doi.org/10.1107/S160053680902296X
work_keys_str_mv AT sørensenhenningosholm 4bromoselenoanisole
AT stuhrhansennicolai 4bromoselenoanisole

Ejemplares similares