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[μ-Bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis­[difluoridoboron(III)]

In the title compound, C(20)H(18)B(2)F(4)N(6), the bis­(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene molecule is bis­ected by a symmetry centre midway between the central N atoms of the diazene group. Each of the symmetry-related halves of the molecule binds to a B atom through an N,N′-bite. Two termi...

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Detalles Bibliográficos
Autores principales: Li, Xin-Sheng, Mo, Juan, Yuan, Li, Liu, Jian-Hua, Zhang, Su-Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969392/
https://www.ncbi.nlm.nih.gov/pubmed/21582932
http://dx.doi.org/10.1107/S1600536809022491
Descripción
Sumario:In the title compound, C(20)H(18)B(2)F(4)N(6), the bis­(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene molecule is bis­ected by a symmetry centre midway between the central N atoms of the diazene group. Each of the symmetry-related halves of the molecule binds to a B atom through an N,N′-bite. Two terminal F ions complete the distorted BN(2)F(2) tetra­hedral geometry around each B atom. The BF(2) plane is almost perpendicular to the boron–naphthyridine ring plane, with a dihedral angle of 87.8 (2)°. The main inter­actions in the crystal structure are some C—H⋯F hydrogen bonds and π–π contacts between 1,8-naphthyridine rings [centroid–centroid distance = 4.005 (1) Å].