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[μ-Bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis­[difluoridoboron(III)]

In the title compound, C(20)H(18)B(2)F(4)N(6), the bis­(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene molecule is bis­ected by a symmetry centre midway between the central N atoms of the diazene group. Each of the symmetry-related halves of the molecule binds to a B atom through an N,N′-bite. Two termi...

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Detalles Bibliográficos
Autores principales: Li, Xin-Sheng, Mo, Juan, Yuan, Li, Liu, Jian-Hua, Zhang, Su-Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969392/
https://www.ncbi.nlm.nih.gov/pubmed/21582932
http://dx.doi.org/10.1107/S1600536809022491
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author Li, Xin-Sheng
Mo, Juan
Yuan, Li
Liu, Jian-Hua
Zhang, Su-Mei
author_facet Li, Xin-Sheng
Mo, Juan
Yuan, Li
Liu, Jian-Hua
Zhang, Su-Mei
author_sort Li, Xin-Sheng
collection PubMed
description In the title compound, C(20)H(18)B(2)F(4)N(6), the bis­(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene molecule is bis­ected by a symmetry centre midway between the central N atoms of the diazene group. Each of the symmetry-related halves of the molecule binds to a B atom through an N,N′-bite. Two terminal F ions complete the distorted BN(2)F(2) tetra­hedral geometry around each B atom. The BF(2) plane is almost perpendicular to the boron–naphthyridine ring plane, with a dihedral angle of 87.8 (2)°. The main inter­actions in the crystal structure are some C—H⋯F hydrogen bonds and π–π contacts between 1,8-naphthyridine rings [centroid–centroid distance = 4.005 (1) Å].
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spelling pubmed-29693922010-12-30 [μ-Bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis­[difluoridoboron(III)] Li, Xin-Sheng Mo, Juan Yuan, Li Liu, Jian-Hua Zhang, Su-Mei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(18)B(2)F(4)N(6), the bis­(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene molecule is bis­ected by a symmetry centre midway between the central N atoms of the diazene group. Each of the symmetry-related halves of the molecule binds to a B atom through an N,N′-bite. Two terminal F ions complete the distorted BN(2)F(2) tetra­hedral geometry around each B atom. The BF(2) plane is almost perpendicular to the boron–naphthyridine ring plane, with a dihedral angle of 87.8 (2)°. The main inter­actions in the crystal structure are some C—H⋯F hydrogen bonds and π–π contacts between 1,8-naphthyridine rings [centroid–centroid distance = 4.005 (1) Å]. International Union of Crystallography 2009-06-24 /pmc/articles/PMC2969392/ /pubmed/21582932 http://dx.doi.org/10.1107/S1600536809022491 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Xin-Sheng
Mo, Juan
Yuan, Li
Liu, Jian-Hua
Zhang, Su-Mei
[μ-Bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis­[difluoridoboron(III)]
title [μ-Bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis­[difluoridoboron(III)]
title_full [μ-Bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis­[difluoridoboron(III)]
title_fullStr [μ-Bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis­[difluoridoboron(III)]
title_full_unstemmed [μ-Bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis­[difluoridoboron(III)]
title_short [μ-Bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis­[difluoridoboron(III)]
title_sort [μ-bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis­[difluoridoboron(iii)]
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969392/
https://www.ncbi.nlm.nih.gov/pubmed/21582932
http://dx.doi.org/10.1107/S1600536809022491
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