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[μ-Bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis[difluoridoboron(III)]
In the title compound, C(20)H(18)B(2)F(4)N(6), the bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene molecule is bisected by a symmetry centre midway between the central N atoms of the diazene group. Each of the symmetry-related halves of the molecule binds to a B atom through an N,N′-bite. Two termi...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969392/ https://www.ncbi.nlm.nih.gov/pubmed/21582932 http://dx.doi.org/10.1107/S1600536809022491 |
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author | Li, Xin-Sheng Mo, Juan Yuan, Li Liu, Jian-Hua Zhang, Su-Mei |
author_facet | Li, Xin-Sheng Mo, Juan Yuan, Li Liu, Jian-Hua Zhang, Su-Mei |
author_sort | Li, Xin-Sheng |
collection | PubMed |
description | In the title compound, C(20)H(18)B(2)F(4)N(6), the bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene molecule is bisected by a symmetry centre midway between the central N atoms of the diazene group. Each of the symmetry-related halves of the molecule binds to a B atom through an N,N′-bite. Two terminal F ions complete the distorted BN(2)F(2) tetrahedral geometry around each B atom. The BF(2) plane is almost perpendicular to the boron–naphthyridine ring plane, with a dihedral angle of 87.8 (2)°. The main interactions in the crystal structure are some C—H⋯F hydrogen bonds and π–π contacts between 1,8-naphthyridine rings [centroid–centroid distance = 4.005 (1) Å]. |
format | Text |
id | pubmed-2969392 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29693922010-12-30 [μ-Bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis[difluoridoboron(III)] Li, Xin-Sheng Mo, Juan Yuan, Li Liu, Jian-Hua Zhang, Su-Mei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(18)B(2)F(4)N(6), the bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene molecule is bisected by a symmetry centre midway between the central N atoms of the diazene group. Each of the symmetry-related halves of the molecule binds to a B atom through an N,N′-bite. Two terminal F ions complete the distorted BN(2)F(2) tetrahedral geometry around each B atom. The BF(2) plane is almost perpendicular to the boron–naphthyridine ring plane, with a dihedral angle of 87.8 (2)°. The main interactions in the crystal structure are some C—H⋯F hydrogen bonds and π–π contacts between 1,8-naphthyridine rings [centroid–centroid distance = 4.005 (1) Å]. International Union of Crystallography 2009-06-24 /pmc/articles/PMC2969392/ /pubmed/21582932 http://dx.doi.org/10.1107/S1600536809022491 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Li, Xin-Sheng Mo, Juan Yuan, Li Liu, Jian-Hua Zhang, Su-Mei [μ-Bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis[difluoridoboron(III)] |
title | [μ-Bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis[difluoridoboron(III)] |
title_full | [μ-Bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis[difluoridoboron(III)] |
title_fullStr | [μ-Bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis[difluoridoboron(III)] |
title_full_unstemmed | [μ-Bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis[difluoridoboron(III)] |
title_short | [μ-Bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis[difluoridoboron(III)] |
title_sort | [μ-bis(5,7-dimethyl-1,8-naphthyridin-2-yl)diazene]bis[difluoridoboron(iii)] |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969392/ https://www.ncbi.nlm.nih.gov/pubmed/21582932 http://dx.doi.org/10.1107/S1600536809022491 |
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