N-Benzyl­idenenordehydro­abietylamine

The title compound [systematic name: (1R,4aS,10aR,E)-N-benzyl­idene-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa­hydro­phenanthren-1-amine], C(26)H(33)N, has been synthesized from nor-dehydro­abietylamine and benzaldehyde. The two cyclo­hexane rings form a trans ring junction with classic chai...

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Detalles Bibliográficos
Autores principales: Rao, Xiao-Ping, Wu, Yong, Song, Zhan-Qian, Shang, Shi-Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969393/
https://www.ncbi.nlm.nih.gov/pubmed/21582903
http://dx.doi.org/10.1107/S1600536809022909
Descripción
Sumario:The title compound [systematic name: (1R,4aS,10aR,E)-N-benzyl­idene-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa­hydro­phenanthren-1-amine], C(26)H(33)N, has been synthesized from nor-dehydro­abietylamine and benzaldehyde. The two cyclo­hexane rings form a trans ring junction with classic chair and half-chair conformations, respectively, the two methyl groups are on the same side of tricyclic hydro­phenanthrene structure. The dihedral angle between two benzene rings is 44.2 (4)°. The C=N bond is in an E configuration.

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