N-Benzyl­idenenordehydro­abietylamine

The title compound [systematic name: (1R,4aS,10aR,E)-N-benzyl­idene-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa­hydro­phenanthren-1-amine], C(26)H(33)N, has been synthesized from nor-dehydro­abietylamine and benzaldehyde. The two cyclo­hexane rings form a trans ring junction with classic chai...

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Detalles Bibliográficos
Autores principales: Rao, Xiao-Ping, Wu, Yong, Song, Zhan-Qian, Shang, Shi-Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969393/
https://www.ncbi.nlm.nih.gov/pubmed/21582903
http://dx.doi.org/10.1107/S1600536809022909
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author Rao, Xiao-Ping
Wu, Yong
Song, Zhan-Qian
Shang, Shi-Bin
author_facet Rao, Xiao-Ping
Wu, Yong
Song, Zhan-Qian
Shang, Shi-Bin
author_sort Rao, Xiao-Ping
collection PubMed
description The title compound [systematic name: (1R,4aS,10aR,E)-N-benzyl­idene-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa­hydro­phenanthren-1-amine], C(26)H(33)N, has been synthesized from nor-dehydro­abietylamine and benzaldehyde. The two cyclo­hexane rings form a trans ring junction with classic chair and half-chair conformations, respectively, the two methyl groups are on the same side of tricyclic hydro­phenanthrene structure. The dihedral angle between two benzene rings is 44.2 (4)°. The C=N bond is in an E configuration.
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spelling pubmed-29693932010-12-30 N-Benzyl­idenenordehydro­abietylamine Rao, Xiao-Ping Wu, Yong Song, Zhan-Qian Shang, Shi-Bin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound [systematic name: (1R,4aS,10aR,E)-N-benzyl­idene-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa­hydro­phenanthren-1-amine], C(26)H(33)N, has been synthesized from nor-dehydro­abietylamine and benzaldehyde. The two cyclo­hexane rings form a trans ring junction with classic chair and half-chair conformations, respectively, the two methyl groups are on the same side of tricyclic hydro­phenanthrene structure. The dihedral angle between two benzene rings is 44.2 (4)°. The C=N bond is in an E configuration. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969393/ /pubmed/21582903 http://dx.doi.org/10.1107/S1600536809022909 Text en © Rao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rao, Xiao-Ping
Wu, Yong
Song, Zhan-Qian
Shang, Shi-Bin
N-Benzyl­idenenordehydro­abietylamine
title N-Benzyl­idenenordehydro­abietylamine
title_full N-Benzyl­idenenordehydro­abietylamine
title_fullStr N-Benzyl­idenenordehydro­abietylamine
title_full_unstemmed N-Benzyl­idenenordehydro­abietylamine
title_short N-Benzyl­idenenordehydro­abietylamine
title_sort n-benzyl­idenenordehydro­abietylamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969393/
https://www.ncbi.nlm.nih.gov/pubmed/21582903
http://dx.doi.org/10.1107/S1600536809022909
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AT wuyong nbenzylidenenordehydroabietylamine
AT songzhanqian nbenzylidenenordehydroabietylamine
AT shangshibin nbenzylidenenordehydroabietylamine

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