Bis(thio­semicarbazide)nickel(II) bis­[2-(thio­semicarbazonometh­yl)benzene­sulfonate] dihydrate

In the title compound, [Ni(CH(5)N(3)S)(2)](C(8)H(8)N(3)O(3)S(2))(2)·2H(2)O, the Ni(II) atom lies on a inversion centre and is four-coordinated by two N and two S atoms of two thio­semicarbazide ligands in an almost square-planar coordination. In the crystal structure, the molecules are linked into a...

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Detalles Bibliográficos
Autores principales: Zhang, Wei, Chen, Yuan-Tao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969405/
https://www.ncbi.nlm.nih.gov/pubmed/21582704
http://dx.doi.org/10.1107/S1600536809022144
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author Zhang, Wei
Chen, Yuan-Tao
author_facet Zhang, Wei
Chen, Yuan-Tao
author_sort Zhang, Wei
collection PubMed
description In the title compound, [Ni(CH(5)N(3)S)(2)](C(8)H(8)N(3)O(3)S(2))(2)·2H(2)O, the Ni(II) atom lies on a inversion centre and is four-coordinated by two N and two S atoms of two thio­semicarbazide ligands in an almost square-planar coordination. In the crystal structure, the molecules are linked into a three-dimensional network via C—H⋯O, C—H⋯N, N—H⋯O, N—H⋯S and O—H⋯O hydrogen bonds.
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spelling pubmed-29694052010-12-30 Bis(thio­semicarbazide)nickel(II) bis­[2-(thio­semicarbazonometh­yl)benzene­sulfonate] dihydrate Zhang, Wei Chen, Yuan-Tao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(CH(5)N(3)S)(2)](C(8)H(8)N(3)O(3)S(2))(2)·2H(2)O, the Ni(II) atom lies on a inversion centre and is four-coordinated by two N and two S atoms of two thio­semicarbazide ligands in an almost square-planar coordination. In the crystal structure, the molecules are linked into a three-dimensional network via C—H⋯O, C—H⋯N, N—H⋯O, N—H⋯S and O—H⋯O hydrogen bonds. International Union of Crystallography 2009-06-13 /pmc/articles/PMC2969405/ /pubmed/21582704 http://dx.doi.org/10.1107/S1600536809022144 Text en © Zhang and Chen 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Wei
Chen, Yuan-Tao
Bis(thio­semicarbazide)nickel(II) bis­[2-(thio­semicarbazonometh­yl)benzene­sulfonate] dihydrate
title Bis(thio­semicarbazide)nickel(II) bis­[2-(thio­semicarbazonometh­yl)benzene­sulfonate] dihydrate
title_full Bis(thio­semicarbazide)nickel(II) bis­[2-(thio­semicarbazonometh­yl)benzene­sulfonate] dihydrate
title_fullStr Bis(thio­semicarbazide)nickel(II) bis­[2-(thio­semicarbazonometh­yl)benzene­sulfonate] dihydrate
title_full_unstemmed Bis(thio­semicarbazide)nickel(II) bis­[2-(thio­semicarbazonometh­yl)benzene­sulfonate] dihydrate
title_short Bis(thio­semicarbazide)nickel(II) bis­[2-(thio­semicarbazonometh­yl)benzene­sulfonate] dihydrate
title_sort bis(thio­semicarbazide)nickel(ii) bis­[2-(thio­semicarbazonometh­yl)benzene­sulfonate] dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969405/
https://www.ncbi.nlm.nih.gov/pubmed/21582704
http://dx.doi.org/10.1107/S1600536809022144
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