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2,3-Diamino­pyridinium benzoate

In the title compound, C(5)H(8)N(3) (+)·C(7)H(5)O(2) (−), the pyridine N atom is protonated. The carboxyl­ate group of the benzoate anion is twisted away from the attached ring by 10.91 (9)°. In the crystal structure, N—H⋯O hydrogen bonds between 2,3-diamino­pyridinium cations and benzoate anions, a...

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Detalles Bibliográficos
Autores principales: Balasubramani, Kasthuri, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969407/
https://www.ncbi.nlm.nih.gov/pubmed/21582810
http://dx.doi.org/10.1107/S1600536809021011
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author Balasubramani, Kasthuri
Fun, Hoong-Kun
author_facet Balasubramani, Kasthuri
Fun, Hoong-Kun
author_sort Balasubramani, Kasthuri
collection PubMed
description In the title compound, C(5)H(8)N(3) (+)·C(7)H(5)O(2) (−), the pyridine N atom is protonated. The carboxyl­ate group of the benzoate anion is twisted away from the attached ring by 10.91 (9)°. In the crystal structure, N—H⋯O hydrogen bonds between 2,3-diamino­pyridinium cations and benzoate anions, and π–π inter­actions between the pyridinium rings [centroid–centroid distance = 3.6467 (9) Å] form a two-dimensional network parallel to (001). In the network, N—H⋯O hydrogen bonds form R (2) (2)(8) and R (2) (1)(7) ring motifs.
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spelling pubmed-29694072010-12-30 2,3-Diamino­pyridinium benzoate Balasubramani, Kasthuri Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(5)H(8)N(3) (+)·C(7)H(5)O(2) (−), the pyridine N atom is protonated. The carboxyl­ate group of the benzoate anion is twisted away from the attached ring by 10.91 (9)°. In the crystal structure, N—H⋯O hydrogen bonds between 2,3-diamino­pyridinium cations and benzoate anions, and π–π inter­actions between the pyridinium rings [centroid–centroid distance = 3.6467 (9) Å] form a two-dimensional network parallel to (001). In the network, N—H⋯O hydrogen bonds form R (2) (2)(8) and R (2) (1)(7) ring motifs. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969407/ /pubmed/21582810 http://dx.doi.org/10.1107/S1600536809021011 Text en © Balasubramani and Fun 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Balasubramani, Kasthuri
Fun, Hoong-Kun
2,3-Diamino­pyridinium benzoate
title 2,3-Diamino­pyridinium benzoate
title_full 2,3-Diamino­pyridinium benzoate
title_fullStr 2,3-Diamino­pyridinium benzoate
title_full_unstemmed 2,3-Diamino­pyridinium benzoate
title_short 2,3-Diamino­pyridinium benzoate
title_sort 2,3-diamino­pyridinium benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969407/
https://www.ncbi.nlm.nih.gov/pubmed/21582810
http://dx.doi.org/10.1107/S1600536809021011
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