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2,3-Diaminopyridinium benzoate
In the title compound, C(5)H(8)N(3) (+)·C(7)H(5)O(2) (−), the pyridine N atom is protonated. The carboxylate group of the benzoate anion is twisted away from the attached ring by 10.91 (9)°. In the crystal structure, N—H⋯O hydrogen bonds between 2,3-diaminopyridinium cations and benzoate anions, a...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969407/ https://www.ncbi.nlm.nih.gov/pubmed/21582810 http://dx.doi.org/10.1107/S1600536809021011 |
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author | Balasubramani, Kasthuri Fun, Hoong-Kun |
author_facet | Balasubramani, Kasthuri Fun, Hoong-Kun |
author_sort | Balasubramani, Kasthuri |
collection | PubMed |
description | In the title compound, C(5)H(8)N(3) (+)·C(7)H(5)O(2) (−), the pyridine N atom is protonated. The carboxylate group of the benzoate anion is twisted away from the attached ring by 10.91 (9)°. In the crystal structure, N—H⋯O hydrogen bonds between 2,3-diaminopyridinium cations and benzoate anions, and π–π interactions between the pyridinium rings [centroid–centroid distance = 3.6467 (9) Å] form a two-dimensional network parallel to (001). In the network, N—H⋯O hydrogen bonds form R (2) (2)(8) and R (2) (1)(7) ring motifs. |
format | Text |
id | pubmed-2969407 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29694072010-12-30 2,3-Diaminopyridinium benzoate Balasubramani, Kasthuri Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(5)H(8)N(3) (+)·C(7)H(5)O(2) (−), the pyridine N atom is protonated. The carboxylate group of the benzoate anion is twisted away from the attached ring by 10.91 (9)°. In the crystal structure, N—H⋯O hydrogen bonds between 2,3-diaminopyridinium cations and benzoate anions, and π–π interactions between the pyridinium rings [centroid–centroid distance = 3.6467 (9) Å] form a two-dimensional network parallel to (001). In the network, N—H⋯O hydrogen bonds form R (2) (2)(8) and R (2) (1)(7) ring motifs. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969407/ /pubmed/21582810 http://dx.doi.org/10.1107/S1600536809021011 Text en © Balasubramani and Fun 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Balasubramani, Kasthuri Fun, Hoong-Kun 2,3-Diaminopyridinium benzoate |
title | 2,3-Diaminopyridinium benzoate |
title_full | 2,3-Diaminopyridinium benzoate |
title_fullStr | 2,3-Diaminopyridinium benzoate |
title_full_unstemmed | 2,3-Diaminopyridinium benzoate |
title_short | 2,3-Diaminopyridinium benzoate |
title_sort | 2,3-diaminopyridinium benzoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969407/ https://www.ncbi.nlm.nih.gov/pubmed/21582810 http://dx.doi.org/10.1107/S1600536809021011 |
work_keys_str_mv | AT balasubramanikasthuri 23diaminopyridiniumbenzoate AT funhoongkun 23diaminopyridiniumbenzoate |