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2-p-Tolyl-1-p-tolylmethyl-1H-benzimidazole
The asymmetric unit of the title compound, C(22)H(20)N(2), contains two crystallographically independent molecules in which the planar benzimidazole ring systems are oriented with respect to the adjacent tolyl rings at dihedral angles of 47.08 (8)/76.85 (8) and 39.52 (9)/87.49 (9)°, while the dihed...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969414/ https://www.ncbi.nlm.nih.gov/pubmed/21582944 http://dx.doi.org/10.1107/S1600536809021175 |
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author | Liu, Ting |
author_facet | Liu, Ting |
author_sort | Liu, Ting |
collection | PubMed |
description | The asymmetric unit of the title compound, C(22)H(20)N(2), contains two crystallographically independent molecules in which the planar benzimidazole ring systems are oriented with respect to the adjacent tolyl rings at dihedral angles of 47.08 (8)/76.85 (8) and 39.52 (9)/87.49 (9)°, while the dihedral angles between the tolyl rings are 73.99 (3) and 81.51 (9)°. In the crystal structure, pairs of intermolecular C—H⋯N interactions link one of the asymmetric molecules into centrosymmetric dimers through R (2) (2)(8) ring motifs. |
format | Text |
id | pubmed-2969414 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29694142010-12-30 2-p-Tolyl-1-p-tolylmethyl-1H-benzimidazole Liu, Ting Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(22)H(20)N(2), contains two crystallographically independent molecules in which the planar benzimidazole ring systems are oriented with respect to the adjacent tolyl rings at dihedral angles of 47.08 (8)/76.85 (8) and 39.52 (9)/87.49 (9)°, while the dihedral angles between the tolyl rings are 73.99 (3) and 81.51 (9)°. In the crystal structure, pairs of intermolecular C—H⋯N interactions link one of the asymmetric molecules into centrosymmetric dimers through R (2) (2)(8) ring motifs. International Union of Crystallography 2009-06-27 /pmc/articles/PMC2969414/ /pubmed/21582944 http://dx.doi.org/10.1107/S1600536809021175 Text en © Ting Liu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Liu, Ting 2-p-Tolyl-1-p-tolylmethyl-1H-benzimidazole |
title | 2-p-Tolyl-1-p-tolylmethyl-1H-benzimidazole |
title_full | 2-p-Tolyl-1-p-tolylmethyl-1H-benzimidazole |
title_fullStr | 2-p-Tolyl-1-p-tolylmethyl-1H-benzimidazole |
title_full_unstemmed | 2-p-Tolyl-1-p-tolylmethyl-1H-benzimidazole |
title_short | 2-p-Tolyl-1-p-tolylmethyl-1H-benzimidazole |
title_sort | 2-p-tolyl-1-p-tolylmethyl-1h-benzimidazole |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969414/ https://www.ncbi.nlm.nih.gov/pubmed/21582944 http://dx.doi.org/10.1107/S1600536809021175 |
work_keys_str_mv | AT liuting 2ptolyl1ptolylmethyl1hbenzimidazole |