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2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime

In the mol­ecule of the title compound, C(16)H(17)N(3)O(2), the planar benzimidazole ring system [maximum deviation = 0.013 (1) Å] is oriented at a dihedral angle of 75.32 (4)° with respect to the furan ring. An intra­molecular C—H⋯O inter­action results in the formation of a planar six-membered rin...

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Detalles Bibliográficos
Autores principales: Özel Güven, Özden, Erdoğan, Taner, Coles, Simon J., Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969417/
https://www.ncbi.nlm.nih.gov/pubmed/21582809
http://dx.doi.org/10.1107/S1600536809020844
Descripción
Sumario:In the mol­ecule of the title compound, C(16)H(17)N(3)O(2), the planar benzimidazole ring system [maximum deviation = 0.013 (1) Å] is oriented at a dihedral angle of 75.32 (4)° with respect to the furan ring. An intra­molecular C—H⋯O inter­action results in the formation of a planar six-membered ring [maximum deviation = 0.019 (15) Å], which is oriented at a dihedral angle of 1.91 (3)° with respect to the adjacent furan ring. In the crystal structure, inter­molecular C—H⋯N inter­actions link the mol­ecules into centrosymmetric R (2) (2)(18) dimers. In addition, the structure is stabilized by π–π contacts between the imidazole rings [centroid–centroid distance = 3.5307 (8) Å] and weak C—H⋯π inter­actions.