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2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime
In the molecule of the title compound, C(16)H(17)N(3)O(2), the planar benzimidazole ring system [maximum deviation = 0.013 (1) Å] is oriented at a dihedral angle of 75.32 (4)° with respect to the furan ring. An intramolecular C—H⋯O interaction results in the formation of a planar six-membered rin...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969417/ https://www.ncbi.nlm.nih.gov/pubmed/21582809 http://dx.doi.org/10.1107/S1600536809020844 |
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author | Özel Güven, Özden Erdoğan, Taner Coles, Simon J. Hökelek, Tuncer |
author_facet | Özel Güven, Özden Erdoğan, Taner Coles, Simon J. Hökelek, Tuncer |
author_sort | Özel Güven, Özden |
collection | PubMed |
description | In the molecule of the title compound, C(16)H(17)N(3)O(2), the planar benzimidazole ring system [maximum deviation = 0.013 (1) Å] is oriented at a dihedral angle of 75.32 (4)° with respect to the furan ring. An intramolecular C—H⋯O interaction results in the formation of a planar six-membered ring [maximum deviation = 0.019 (15) Å], which is oriented at a dihedral angle of 1.91 (3)° with respect to the adjacent furan ring. In the crystal structure, intermolecular C—H⋯N interactions link the molecules into centrosymmetric R (2) (2)(18) dimers. In addition, the structure is stabilized by π–π contacts between the imidazole rings [centroid–centroid distance = 3.5307 (8) Å] and weak C—H⋯π interactions. |
format | Text |
id | pubmed-2969417 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29694172010-12-30 2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime Özel Güven, Özden Erdoğan, Taner Coles, Simon J. Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(16)H(17)N(3)O(2), the planar benzimidazole ring system [maximum deviation = 0.013 (1) Å] is oriented at a dihedral angle of 75.32 (4)° with respect to the furan ring. An intramolecular C—H⋯O interaction results in the formation of a planar six-membered ring [maximum deviation = 0.019 (15) Å], which is oriented at a dihedral angle of 1.91 (3)° with respect to the adjacent furan ring. In the crystal structure, intermolecular C—H⋯N interactions link the molecules into centrosymmetric R (2) (2)(18) dimers. In addition, the structure is stabilized by π–π contacts between the imidazole rings [centroid–centroid distance = 3.5307 (8) Å] and weak C—H⋯π interactions. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969417/ /pubmed/21582809 http://dx.doi.org/10.1107/S1600536809020844 Text en © Özel Güven et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Özel Güven, Özden Erdoğan, Taner Coles, Simon J. Hökelek, Tuncer 2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime |
title | 2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime |
title_full | 2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime |
title_fullStr | 2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime |
title_full_unstemmed | 2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime |
title_short | 2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime |
title_sort | 2-(1h-benzimidazol-1-yl)-1-(2-furyl)ethanone o-propyloxime |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969417/ https://www.ncbi.nlm.nih.gov/pubmed/21582809 http://dx.doi.org/10.1107/S1600536809020844 |
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