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2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime

In the mol­ecule of the title compound, C(16)H(17)N(3)O(2), the planar benzimidazole ring system [maximum deviation = 0.013 (1) Å] is oriented at a dihedral angle of 75.32 (4)° with respect to the furan ring. An intra­molecular C—H⋯O inter­action results in the formation of a planar six-membered rin...

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Detalles Bibliográficos
Autores principales: Özel Güven, Özden, Erdoğan, Taner, Coles, Simon J., Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969417/
https://www.ncbi.nlm.nih.gov/pubmed/21582809
http://dx.doi.org/10.1107/S1600536809020844
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author Özel Güven, Özden
Erdoğan, Taner
Coles, Simon J.
Hökelek, Tuncer
author_facet Özel Güven, Özden
Erdoğan, Taner
Coles, Simon J.
Hökelek, Tuncer
author_sort Özel Güven, Özden
collection PubMed
description In the mol­ecule of the title compound, C(16)H(17)N(3)O(2), the planar benzimidazole ring system [maximum deviation = 0.013 (1) Å] is oriented at a dihedral angle of 75.32 (4)° with respect to the furan ring. An intra­molecular C—H⋯O inter­action results in the formation of a planar six-membered ring [maximum deviation = 0.019 (15) Å], which is oriented at a dihedral angle of 1.91 (3)° with respect to the adjacent furan ring. In the crystal structure, inter­molecular C—H⋯N inter­actions link the mol­ecules into centrosymmetric R (2) (2)(18) dimers. In addition, the structure is stabilized by π–π contacts between the imidazole rings [centroid–centroid distance = 3.5307 (8) Å] and weak C—H⋯π inter­actions.
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spelling pubmed-29694172010-12-30 2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime Özel Güven, Özden Erdoğan, Taner Coles, Simon J. Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(16)H(17)N(3)O(2), the planar benzimidazole ring system [maximum deviation = 0.013 (1) Å] is oriented at a dihedral angle of 75.32 (4)° with respect to the furan ring. An intra­molecular C—H⋯O inter­action results in the formation of a planar six-membered ring [maximum deviation = 0.019 (15) Å], which is oriented at a dihedral angle of 1.91 (3)° with respect to the adjacent furan ring. In the crystal structure, inter­molecular C—H⋯N inter­actions link the mol­ecules into centrosymmetric R (2) (2)(18) dimers. In addition, the structure is stabilized by π–π contacts between the imidazole rings [centroid–centroid distance = 3.5307 (8) Å] and weak C—H⋯π inter­actions. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969417/ /pubmed/21582809 http://dx.doi.org/10.1107/S1600536809020844 Text en © Özel Güven et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Özel Güven, Özden
Erdoğan, Taner
Coles, Simon J.
Hökelek, Tuncer
2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime
title 2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime
title_full 2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime
title_fullStr 2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime
title_full_unstemmed 2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime
title_short 2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime
title_sort 2-(1h-benzimidazol-1-yl)-1-(2-furyl)ethanone o-propyloxime
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969417/
https://www.ncbi.nlm.nih.gov/pubmed/21582809
http://dx.doi.org/10.1107/S1600536809020844
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