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(−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonyl­imino)]dipropanoate

The title compound, C(27)H(27)N(3)O(6), a bis-amide derivative, is also a chiral amino acid ester with l-phenyl­alanine methyl ester groups as amine substituents. The pyridine ring is oriented at dihedral angles of 89.69 (3) and 62.95 (3)° with respect to the phenyl rings, while the dihedral angle b...

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Detalles Bibliográficos
Autores principales: Yin, Shaohong, Cui, Yu, Xia, Guangming, Zhang, Yanju, Sun, Guoxin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969420/
https://www.ncbi.nlm.nih.gov/pubmed/21582964
http://dx.doi.org/10.1107/S1600536809023721
Descripción
Sumario:The title compound, C(27)H(27)N(3)O(6), a bis-amide derivative, is also a chiral amino acid ester with l-phenyl­alanine methyl ester groups as amine substituents. The pyridine ring is oriented at dihedral angles of 89.69 (3) and 62.95 (3)° with respect to the phenyl rings, while the dihedral angle between the phenyl rings is 60.76 (3)°. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains. One of the carbonyl O atoms and one of the meth­oxy CH(3) groups are disordered over two positions. The O atom was refined with occupancies of 0.69 (13) and 0.31 (13), while C and H atoms were refined with occupancies of 0.69 (8) and 0.31 (8).