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(−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonylimino)]dipropanoate
The title compound, C(27)H(27)N(3)O(6), a bis-amide derivative, is also a chiral amino acid ester with l-phenylalanine methyl ester groups as amine substituents. The pyridine ring is oriented at dihedral angles of 89.69 (3) and 62.95 (3)° with respect to the phenyl rings, while the dihedral angle b...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969420/ https://www.ncbi.nlm.nih.gov/pubmed/21582964 http://dx.doi.org/10.1107/S1600536809023721 |
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author | Yin, Shaohong Cui, Yu Xia, Guangming Zhang, Yanju Sun, Guoxin |
author_facet | Yin, Shaohong Cui, Yu Xia, Guangming Zhang, Yanju Sun, Guoxin |
author_sort | Yin, Shaohong |
collection | PubMed |
description | The title compound, C(27)H(27)N(3)O(6), a bis-amide derivative, is also a chiral amino acid ester with l-phenylalanine methyl ester groups as amine substituents. The pyridine ring is oriented at dihedral angles of 89.69 (3) and 62.95 (3)° with respect to the phenyl rings, while the dihedral angle between the phenyl rings is 60.76 (3)°. In the crystal structure, intermolecular N—H⋯O hydrogen bonds link the molecules into chains. One of the carbonyl O atoms and one of the methoxy CH(3) groups are disordered over two positions. The O atom was refined with occupancies of 0.69 (13) and 0.31 (13), while C and H atoms were refined with occupancies of 0.69 (8) and 0.31 (8). |
format | Text |
id | pubmed-2969420 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29694202010-12-30 (−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonylimino)]dipropanoate Yin, Shaohong Cui, Yu Xia, Guangming Zhang, Yanju Sun, Guoxin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(27)H(27)N(3)O(6), a bis-amide derivative, is also a chiral amino acid ester with l-phenylalanine methyl ester groups as amine substituents. The pyridine ring is oriented at dihedral angles of 89.69 (3) and 62.95 (3)° with respect to the phenyl rings, while the dihedral angle between the phenyl rings is 60.76 (3)°. In the crystal structure, intermolecular N—H⋯O hydrogen bonds link the molecules into chains. One of the carbonyl O atoms and one of the methoxy CH(3) groups are disordered over two positions. The O atom was refined with occupancies of 0.69 (13) and 0.31 (13), while C and H atoms were refined with occupancies of 0.69 (8) and 0.31 (8). International Union of Crystallography 2009-06-27 /pmc/articles/PMC2969420/ /pubmed/21582964 http://dx.doi.org/10.1107/S1600536809023721 Text en © Yin et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Yin, Shaohong Cui, Yu Xia, Guangming Zhang, Yanju Sun, Guoxin (−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonylimino)]dipropanoate |
title | (−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonylimino)]dipropanoate |
title_full | (−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonylimino)]dipropanoate |
title_fullStr | (−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonylimino)]dipropanoate |
title_full_unstemmed | (−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonylimino)]dipropanoate |
title_short | (−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonylimino)]dipropanoate |
title_sort | (−)-dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonylimino)]dipropanoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969420/ https://www.ncbi.nlm.nih.gov/pubmed/21582964 http://dx.doi.org/10.1107/S1600536809023721 |
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