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(−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonyl­imino)]dipropanoate

The title compound, C(27)H(27)N(3)O(6), a bis-amide derivative, is also a chiral amino acid ester with l-phenyl­alanine methyl ester groups as amine substituents. The pyridine ring is oriented at dihedral angles of 89.69 (3) and 62.95 (3)° with respect to the phenyl rings, while the dihedral angle b...

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Detalles Bibliográficos
Autores principales: Yin, Shaohong, Cui, Yu, Xia, Guangming, Zhang, Yanju, Sun, Guoxin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969420/
https://www.ncbi.nlm.nih.gov/pubmed/21582964
http://dx.doi.org/10.1107/S1600536809023721
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author Yin, Shaohong
Cui, Yu
Xia, Guangming
Zhang, Yanju
Sun, Guoxin
author_facet Yin, Shaohong
Cui, Yu
Xia, Guangming
Zhang, Yanju
Sun, Guoxin
author_sort Yin, Shaohong
collection PubMed
description The title compound, C(27)H(27)N(3)O(6), a bis-amide derivative, is also a chiral amino acid ester with l-phenyl­alanine methyl ester groups as amine substituents. The pyridine ring is oriented at dihedral angles of 89.69 (3) and 62.95 (3)° with respect to the phenyl rings, while the dihedral angle between the phenyl rings is 60.76 (3)°. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains. One of the carbonyl O atoms and one of the meth­oxy CH(3) groups are disordered over two positions. The O atom was refined with occupancies of 0.69 (13) and 0.31 (13), while C and H atoms were refined with occupancies of 0.69 (8) and 0.31 (8).
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spelling pubmed-29694202010-12-30 (−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonyl­imino)]dipropanoate Yin, Shaohong Cui, Yu Xia, Guangming Zhang, Yanju Sun, Guoxin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(27)H(27)N(3)O(6), a bis-amide derivative, is also a chiral amino acid ester with l-phenyl­alanine methyl ester groups as amine substituents. The pyridine ring is oriented at dihedral angles of 89.69 (3) and 62.95 (3)° with respect to the phenyl rings, while the dihedral angle between the phenyl rings is 60.76 (3)°. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains. One of the carbonyl O atoms and one of the meth­oxy CH(3) groups are disordered over two positions. The O atom was refined with occupancies of 0.69 (13) and 0.31 (13), while C and H atoms were refined with occupancies of 0.69 (8) and 0.31 (8). International Union of Crystallography 2009-06-27 /pmc/articles/PMC2969420/ /pubmed/21582964 http://dx.doi.org/10.1107/S1600536809023721 Text en © Yin et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yin, Shaohong
Cui, Yu
Xia, Guangming
Zhang, Yanju
Sun, Guoxin
(−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonyl­imino)]dipropanoate
title (−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonyl­imino)]dipropanoate
title_full (−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonyl­imino)]dipropanoate
title_fullStr (−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonyl­imino)]dipropanoate
title_full_unstemmed (−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonyl­imino)]dipropanoate
title_short (−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonyl­imino)]dipropanoate
title_sort (−)-dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonyl­imino)]dipropanoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969420/
https://www.ncbi.nlm.nih.gov/pubmed/21582964
http://dx.doi.org/10.1107/S1600536809023721
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