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Diaqua­bis(norfloxacinato)manganese(II) 2,2′-bipyridine solvate tetra­hydrate

In the crystal structure of the title compound {systematic name: diaqua­bis[1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydro­quinoline-3-carboxyl­ato]manganese(II) 2,2′-bipyridine solvate tetra­hydrate}, [Mn(C(16)H(17)FN(3)O(3))(2)(H(2)O)(2)]·C(10)H(8)N(2)·4H(2)O, the pyridone O atom and one ca...

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Detalles Bibliográficos
Autores principales: Wang, Yan-Jun, Lin, Qiu-Yue, Feng, Jie, Wang, Na
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969423/
https://www.ncbi.nlm.nih.gov/pubmed/21582730
http://dx.doi.org/10.1107/S1600536809022831
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author Wang, Yan-Jun
Lin, Qiu-Yue
Feng, Jie
Wang, Na
author_facet Wang, Yan-Jun
Lin, Qiu-Yue
Feng, Jie
Wang, Na
author_sort Wang, Yan-Jun
collection PubMed
description In the crystal structure of the title compound {systematic name: diaqua­bis[1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydro­quinoline-3-carboxyl­ato]manganese(II) 2,2′-bipyridine solvate tetra­hydrate}, [Mn(C(16)H(17)FN(3)O(3))(2)(H(2)O)(2)]·C(10)H(8)N(2)·4H(2)O, the pyridone O atom and one carboxyl­ate O atom of the two norfloxacin ligands are bound to the Mn(II) ion, which is located on an inversion centre, and occupy equatorial positions, while two aqua O atoms lie in apical positions, resulting in a distorted octa­hedral geometry. The crystal packing is stabilized by N—H⋯O and O—H⋯O hydrogen-bonding interactions.
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spelling pubmed-29694232010-12-30 Diaqua­bis(norfloxacinato)manganese(II) 2,2′-bipyridine solvate tetra­hydrate Wang, Yan-Jun Lin, Qiu-Yue Feng, Jie Wang, Na Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound {systematic name: diaqua­bis[1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydro­quinoline-3-carboxyl­ato]manganese(II) 2,2′-bipyridine solvate tetra­hydrate}, [Mn(C(16)H(17)FN(3)O(3))(2)(H(2)O)(2)]·C(10)H(8)N(2)·4H(2)O, the pyridone O atom and one carboxyl­ate O atom of the two norfloxacin ligands are bound to the Mn(II) ion, which is located on an inversion centre, and occupy equatorial positions, while two aqua O atoms lie in apical positions, resulting in a distorted octa­hedral geometry. The crystal packing is stabilized by N—H⋯O and O—H⋯O hydrogen-bonding interactions. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969423/ /pubmed/21582730 http://dx.doi.org/10.1107/S1600536809022831 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Yan-Jun
Lin, Qiu-Yue
Feng, Jie
Wang, Na
Diaqua­bis(norfloxacinato)manganese(II) 2,2′-bipyridine solvate tetra­hydrate
title Diaqua­bis(norfloxacinato)manganese(II) 2,2′-bipyridine solvate tetra­hydrate
title_full Diaqua­bis(norfloxacinato)manganese(II) 2,2′-bipyridine solvate tetra­hydrate
title_fullStr Diaqua­bis(norfloxacinato)manganese(II) 2,2′-bipyridine solvate tetra­hydrate
title_full_unstemmed Diaqua­bis(norfloxacinato)manganese(II) 2,2′-bipyridine solvate tetra­hydrate
title_short Diaqua­bis(norfloxacinato)manganese(II) 2,2′-bipyridine solvate tetra­hydrate
title_sort diaqua­bis(norfloxacinato)manganese(ii) 2,2′-bipyridine solvate tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969423/
https://www.ncbi.nlm.nih.gov/pubmed/21582730
http://dx.doi.org/10.1107/S1600536809022831
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