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Diaquabis(norfloxacinato)manganese(II) 2,2′-bipyridine solvate tetrahydrate
In the crystal structure of the title compound {systematic name: diaquabis[1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato]manganese(II) 2,2′-bipyridine solvate tetrahydrate}, [Mn(C(16)H(17)FN(3)O(3))(2)(H(2)O)(2)]·C(10)H(8)N(2)·4H(2)O, the pyridone O atom and one ca...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969423/ https://www.ncbi.nlm.nih.gov/pubmed/21582730 http://dx.doi.org/10.1107/S1600536809022831 |
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author | Wang, Yan-Jun Lin, Qiu-Yue Feng, Jie Wang, Na |
author_facet | Wang, Yan-Jun Lin, Qiu-Yue Feng, Jie Wang, Na |
author_sort | Wang, Yan-Jun |
collection | PubMed |
description | In the crystal structure of the title compound {systematic name: diaquabis[1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato]manganese(II) 2,2′-bipyridine solvate tetrahydrate}, [Mn(C(16)H(17)FN(3)O(3))(2)(H(2)O)(2)]·C(10)H(8)N(2)·4H(2)O, the pyridone O atom and one carboxylate O atom of the two norfloxacin ligands are bound to the Mn(II) ion, which is located on an inversion centre, and occupy equatorial positions, while two aqua O atoms lie in apical positions, resulting in a distorted octahedral geometry. The crystal packing is stabilized by N—H⋯O and O—H⋯O hydrogen-bonding interactions. |
format | Text |
id | pubmed-2969423 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29694232010-12-30 Diaquabis(norfloxacinato)manganese(II) 2,2′-bipyridine solvate tetrahydrate Wang, Yan-Jun Lin, Qiu-Yue Feng, Jie Wang, Na Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound {systematic name: diaquabis[1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato]manganese(II) 2,2′-bipyridine solvate tetrahydrate}, [Mn(C(16)H(17)FN(3)O(3))(2)(H(2)O)(2)]·C(10)H(8)N(2)·4H(2)O, the pyridone O atom and one carboxylate O atom of the two norfloxacin ligands are bound to the Mn(II) ion, which is located on an inversion centre, and occupy equatorial positions, while two aqua O atoms lie in apical positions, resulting in a distorted octahedral geometry. The crystal packing is stabilized by N—H⋯O and O—H⋯O hydrogen-bonding interactions. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969423/ /pubmed/21582730 http://dx.doi.org/10.1107/S1600536809022831 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Yan-Jun Lin, Qiu-Yue Feng, Jie Wang, Na Diaquabis(norfloxacinato)manganese(II) 2,2′-bipyridine solvate tetrahydrate |
title | Diaquabis(norfloxacinato)manganese(II) 2,2′-bipyridine solvate tetrahydrate |
title_full | Diaquabis(norfloxacinato)manganese(II) 2,2′-bipyridine solvate tetrahydrate |
title_fullStr | Diaquabis(norfloxacinato)manganese(II) 2,2′-bipyridine solvate tetrahydrate |
title_full_unstemmed | Diaquabis(norfloxacinato)manganese(II) 2,2′-bipyridine solvate tetrahydrate |
title_short | Diaquabis(norfloxacinato)manganese(II) 2,2′-bipyridine solvate tetrahydrate |
title_sort | diaquabis(norfloxacinato)manganese(ii) 2,2′-bipyridine solvate tetrahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969423/ https://www.ncbi.nlm.nih.gov/pubmed/21582730 http://dx.doi.org/10.1107/S1600536809022831 |
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