(μ-Acetato){μ-1,3-bis[2-(2-oxidobenzylideneamino)ethyl]-2-(2-oxidophenyl)-1,3-imidazolidine}dizinc(II) ethanol disolvate dihydrate

In the title binuclear compound, [Zn(2)(C(27)H(27)N(4)O(3))(C(2)H(3)O(2))]·2CH(3)CH(2)OH·2H(2)O, both Zn cations adopt distorted ZnO(3)N(2) trigonal-bipyramidal geometries with one N atom in a axial site and one N atom in an equatorial site, arising from coordination by the N,N,N,N,O,O,O-hepta­denta...

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Detalles Bibliográficos
Autores principales: Lu, Xiao-Ping, Zhu, Miao-Li, Lu, Li-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969424/
https://www.ncbi.nlm.nih.gov/pubmed/21582672
http://dx.doi.org/10.1107/S1600536809020716
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author Lu, Xiao-Ping
Zhu, Miao-Li
Lu, Li-Ping
author_facet Lu, Xiao-Ping
Zhu, Miao-Li
Lu, Li-Ping
author_sort Lu, Xiao-Ping
collection PubMed
description In the title binuclear compound, [Zn(2)(C(27)H(27)N(4)O(3))(C(2)H(3)O(2))]·2CH(3)CH(2)OH·2H(2)O, both Zn cations adopt distorted ZnO(3)N(2) trigonal-bipyramidal geometries with one N atom in a axial site and one N atom in an equatorial site, arising from coordination by the N,N,N,N,O,O,O-hepta­dentate ligand and a bridging acetate ion. In the crystal, inter­molecular O—H⋯O hydrogen bonds link the component units into a three-dimensional network. Two short C—H⋯O contacts are also seen.
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spelling pubmed-29694242010-12-30 (μ-Acetato){μ-1,3-bis[2-(2-oxidobenzylideneamino)ethyl]-2-(2-oxidophenyl)-1,3-imidazolidine}dizinc(II) ethanol disolvate dihydrate Lu, Xiao-Ping Zhu, Miao-Li Lu, Li-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title binuclear compound, [Zn(2)(C(27)H(27)N(4)O(3))(C(2)H(3)O(2))]·2CH(3)CH(2)OH·2H(2)O, both Zn cations adopt distorted ZnO(3)N(2) trigonal-bipyramidal geometries with one N atom in a axial site and one N atom in an equatorial site, arising from coordination by the N,N,N,N,O,O,O-hepta­dentate ligand and a bridging acetate ion. In the crystal, inter­molecular O—H⋯O hydrogen bonds link the component units into a three-dimensional network. Two short C—H⋯O contacts are also seen. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969424/ /pubmed/21582672 http://dx.doi.org/10.1107/S1600536809020716 Text en © Lu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lu, Xiao-Ping
Zhu, Miao-Li
Lu, Li-Ping
(μ-Acetato){μ-1,3-bis[2-(2-oxidobenzylideneamino)ethyl]-2-(2-oxidophenyl)-1,3-imidazolidine}dizinc(II) ethanol disolvate dihydrate
title (μ-Acetato){μ-1,3-bis[2-(2-oxidobenzylideneamino)ethyl]-2-(2-oxidophenyl)-1,3-imidazolidine}dizinc(II) ethanol disolvate dihydrate
title_full (μ-Acetato){μ-1,3-bis[2-(2-oxidobenzylideneamino)ethyl]-2-(2-oxidophenyl)-1,3-imidazolidine}dizinc(II) ethanol disolvate dihydrate
title_fullStr (μ-Acetato){μ-1,3-bis[2-(2-oxidobenzylideneamino)ethyl]-2-(2-oxidophenyl)-1,3-imidazolidine}dizinc(II) ethanol disolvate dihydrate
title_full_unstemmed (μ-Acetato){μ-1,3-bis[2-(2-oxidobenzylideneamino)ethyl]-2-(2-oxidophenyl)-1,3-imidazolidine}dizinc(II) ethanol disolvate dihydrate
title_short (μ-Acetato){μ-1,3-bis[2-(2-oxidobenzylideneamino)ethyl]-2-(2-oxidophenyl)-1,3-imidazolidine}dizinc(II) ethanol disolvate dihydrate
title_sort (μ-acetato){μ-1,3-bis[2-(2-oxidobenzylideneamino)ethyl]-2-(2-oxidophenyl)-1,3-imidazolidine}dizinc(ii) ethanol disolvate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969424/
https://www.ncbi.nlm.nih.gov/pubmed/21582672
http://dx.doi.org/10.1107/S1600536809020716
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AT zhumiaoli macetatom13bis22oxidobenzylideneaminoethyl22oxidophenyl13imidazolidinedizinciiethanoldisolvatedihydrate
AT luliping macetatom13bis22oxidobenzylideneaminoethyl22oxidophenyl13imidazolidinedizinciiethanoldisolvatedihydrate

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