4-(1-Adamantylmeth­yl)-N-(2-chloro-9-isopropyl-9H-purin-6-yl)aniline

The asymmetric unit of the title compound, C(25)H(30)ClN(5), consists of two mol­ecules with slightly different geometrical parameters. The dihedral angles between the purine and benzene rings are 39.54 (5) and 23.69 (5)° in the two mol­ecules. The adamantane cages consist of three fused cyclo­hexan...

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Detalles Bibliográficos
Autores principales: Rouchal, Michal, Nečas, Marek, Vícha, Robert
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969425/
https://www.ncbi.nlm.nih.gov/pubmed/21582935
http://dx.doi.org/10.1107/S1600536809023629
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author Rouchal, Michal
Nečas, Marek
Vícha, Robert
author_facet Rouchal, Michal
Nečas, Marek
Vícha, Robert
author_sort Rouchal, Michal
collection PubMed
description The asymmetric unit of the title compound, C(25)H(30)ClN(5), consists of two mol­ecules with slightly different geometrical parameters. The dihedral angles between the purine and benzene rings are 39.54 (5) and 23.69 (5)° in the two mol­ecules. The adamantane cages consist of three fused cyclo­hexane rings in classical chair conformations, with C—C—C angles in the range 108 (2)–111 (2)°. In the crystal, mol­ecules are linked into dimers via two N—H⋯N hydrogen bonds.
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spelling pubmed-29694252010-12-30 4-(1-Adamantylmeth­yl)-N-(2-chloro-9-isopropyl-9H-purin-6-yl)aniline Rouchal, Michal Nečas, Marek Vícha, Robert Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(25)H(30)ClN(5), consists of two mol­ecules with slightly different geometrical parameters. The dihedral angles between the purine and benzene rings are 39.54 (5) and 23.69 (5)° in the two mol­ecules. The adamantane cages consist of three fused cyclo­hexane rings in classical chair conformations, with C—C—C angles in the range 108 (2)–111 (2)°. In the crystal, mol­ecules are linked into dimers via two N—H⋯N hydrogen bonds. International Union of Crystallography 2009-06-24 /pmc/articles/PMC2969425/ /pubmed/21582935 http://dx.doi.org/10.1107/S1600536809023629 Text en © Rouchal et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rouchal, Michal
Nečas, Marek
Vícha, Robert
4-(1-Adamantylmeth­yl)-N-(2-chloro-9-isopropyl-9H-purin-6-yl)aniline
title 4-(1-Adamantylmeth­yl)-N-(2-chloro-9-isopropyl-9H-purin-6-yl)aniline
title_full 4-(1-Adamantylmeth­yl)-N-(2-chloro-9-isopropyl-9H-purin-6-yl)aniline
title_fullStr 4-(1-Adamantylmeth­yl)-N-(2-chloro-9-isopropyl-9H-purin-6-yl)aniline
title_full_unstemmed 4-(1-Adamantylmeth­yl)-N-(2-chloro-9-isopropyl-9H-purin-6-yl)aniline
title_short 4-(1-Adamantylmeth­yl)-N-(2-chloro-9-isopropyl-9H-purin-6-yl)aniline
title_sort 4-(1-adamantylmeth­yl)-n-(2-chloro-9-isopropyl-9h-purin-6-yl)aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969425/
https://www.ncbi.nlm.nih.gov/pubmed/21582935
http://dx.doi.org/10.1107/S1600536809023629
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AT vicharobert 41adamantylmethyln2chloro9isopropyl9hpurin6ylaniline

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