Cargando…

{2,2′-[1,1′-(Ethyl­enedioxy­dinitrilo)diethyl­idyne]di-1-naphtholato}nickel(II)

In the title complex, [Ni(C(26)H(22)N(2)O(4))], the Ni(II) atom has a slight distortion toward tetra­hedral geometry from a square-planar structure, coordinated by two O and two N atoms of the tetra­dentate salen-type bis­oxime 2,2′-[1,1′-(ethyl­enedioxy­dinitrilo)diethyl­idyne]di-1-naphtholate (L (...

Descripción completa

Detalles Bibliográficos
Autores principales: Dong, Wen-Kui, Wu, Jian-Chao, Yao, Jian, Gong, Shang-Sheng, Tong, Jun-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969427/
https://www.ncbi.nlm.nih.gov/pubmed/21582728
http://dx.doi.org/10.1107/S1600536809023149
_version_ 1782190146855108608
author Dong, Wen-Kui
Wu, Jian-Chao
Yao, Jian
Gong, Shang-Sheng
Tong, Jun-Feng
author_facet Dong, Wen-Kui
Wu, Jian-Chao
Yao, Jian
Gong, Shang-Sheng
Tong, Jun-Feng
author_sort Dong, Wen-Kui
collection PubMed
description In the title complex, [Ni(C(26)H(22)N(2)O(4))], the Ni(II) atom has a slight distortion toward tetra­hedral geometry from a square-planar structure, coordinated by two O and two N atoms of the tetra­dentate salen-type bis­oxime 2,2′-[1,1′-(ethyl­enedioxy­dinitrilo)diethyl­idyne]di-1-naphtholate (L (2−)) unit, with a mean deviation of 0.022 Å from the N(2)O(2) plane. The N- and O-donor atoms are mutually cis. The dihedral angle between two naphthalene systems of the L (2−) ligand is 67.59 (4)°. The crystal structure is stabilized by inter­molecular C—H⋯O and C—H⋯π inter­actions, which link neighbouring mol­ecules into extended chains along the b axis.
format Text
id pubmed-2969427
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29694272010-12-30 {2,2′-[1,1′-(Ethyl­enedioxy­dinitrilo)diethyl­idyne]di-1-naphtholato}nickel(II) Dong, Wen-Kui Wu, Jian-Chao Yao, Jian Gong, Shang-Sheng Tong, Jun-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(26)H(22)N(2)O(4))], the Ni(II) atom has a slight distortion toward tetra­hedral geometry from a square-planar structure, coordinated by two O and two N atoms of the tetra­dentate salen-type bis­oxime 2,2′-[1,1′-(ethyl­enedioxy­dinitrilo)diethyl­idyne]di-1-naphtholate (L (2−)) unit, with a mean deviation of 0.022 Å from the N(2)O(2) plane. The N- and O-donor atoms are mutually cis. The dihedral angle between two naphthalene systems of the L (2−) ligand is 67.59 (4)°. The crystal structure is stabilized by inter­molecular C—H⋯O and C—H⋯π inter­actions, which link neighbouring mol­ecules into extended chains along the b axis. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969427/ /pubmed/21582728 http://dx.doi.org/10.1107/S1600536809023149 Text en © Dong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dong, Wen-Kui
Wu, Jian-Chao
Yao, Jian
Gong, Shang-Sheng
Tong, Jun-Feng
{2,2′-[1,1′-(Ethyl­enedioxy­dinitrilo)diethyl­idyne]di-1-naphtholato}nickel(II)
title {2,2′-[1,1′-(Ethyl­enedioxy­dinitrilo)diethyl­idyne]di-1-naphtholato}nickel(II)
title_full {2,2′-[1,1′-(Ethyl­enedioxy­dinitrilo)diethyl­idyne]di-1-naphtholato}nickel(II)
title_fullStr {2,2′-[1,1′-(Ethyl­enedioxy­dinitrilo)diethyl­idyne]di-1-naphtholato}nickel(II)
title_full_unstemmed {2,2′-[1,1′-(Ethyl­enedioxy­dinitrilo)diethyl­idyne]di-1-naphtholato}nickel(II)
title_short {2,2′-[1,1′-(Ethyl­enedioxy­dinitrilo)diethyl­idyne]di-1-naphtholato}nickel(II)
title_sort {2,2′-[1,1′-(ethyl­enedioxy­dinitrilo)diethyl­idyne]di-1-naphtholato}nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969427/
https://www.ncbi.nlm.nih.gov/pubmed/21582728
http://dx.doi.org/10.1107/S1600536809023149
work_keys_str_mv AT dongwenkui 2211ethylenedioxydinitrilodiethylidynedi1naphtholatonickelii
AT wujianchao 2211ethylenedioxydinitrilodiethylidynedi1naphtholatonickelii
AT yaojian 2211ethylenedioxydinitrilodiethylidynedi1naphtholatonickelii
AT gongshangsheng 2211ethylenedioxydinitrilodiethylidynedi1naphtholatonickelii
AT tongjunfeng 2211ethylenedioxydinitrilodiethylidynedi1naphtholatonickelii