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{2,2′-[1,1′-(Ethylenedioxydinitrilo)diethylidyne]di-1-naphtholato}nickel(II)
In the title complex, [Ni(C(26)H(22)N(2)O(4))], the Ni(II) atom has a slight distortion toward tetrahedral geometry from a square-planar structure, coordinated by two O and two N atoms of the tetradentate salen-type bisoxime 2,2′-[1,1′-(ethylenedioxydinitrilo)diethylidyne]di-1-naphtholate (L (...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969427/ https://www.ncbi.nlm.nih.gov/pubmed/21582728 http://dx.doi.org/10.1107/S1600536809023149 |
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author | Dong, Wen-Kui Wu, Jian-Chao Yao, Jian Gong, Shang-Sheng Tong, Jun-Feng |
author_facet | Dong, Wen-Kui Wu, Jian-Chao Yao, Jian Gong, Shang-Sheng Tong, Jun-Feng |
author_sort | Dong, Wen-Kui |
collection | PubMed |
description | In the title complex, [Ni(C(26)H(22)N(2)O(4))], the Ni(II) atom has a slight distortion toward tetrahedral geometry from a square-planar structure, coordinated by two O and two N atoms of the tetradentate salen-type bisoxime 2,2′-[1,1′-(ethylenedioxydinitrilo)diethylidyne]di-1-naphtholate (L (2−)) unit, with a mean deviation of 0.022 Å from the N(2)O(2) plane. The N- and O-donor atoms are mutually cis. The dihedral angle between two naphthalene systems of the L (2−) ligand is 67.59 (4)°. The crystal structure is stabilized by intermolecular C—H⋯O and C—H⋯π interactions, which link neighbouring molecules into extended chains along the b axis. |
format | Text |
id | pubmed-2969427 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29694272010-12-30 {2,2′-[1,1′-(Ethylenedioxydinitrilo)diethylidyne]di-1-naphtholato}nickel(II) Dong, Wen-Kui Wu, Jian-Chao Yao, Jian Gong, Shang-Sheng Tong, Jun-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(26)H(22)N(2)O(4))], the Ni(II) atom has a slight distortion toward tetrahedral geometry from a square-planar structure, coordinated by two O and two N atoms of the tetradentate salen-type bisoxime 2,2′-[1,1′-(ethylenedioxydinitrilo)diethylidyne]di-1-naphtholate (L (2−)) unit, with a mean deviation of 0.022 Å from the N(2)O(2) plane. The N- and O-donor atoms are mutually cis. The dihedral angle between two naphthalene systems of the L (2−) ligand is 67.59 (4)°. The crystal structure is stabilized by intermolecular C—H⋯O and C—H⋯π interactions, which link neighbouring molecules into extended chains along the b axis. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969427/ /pubmed/21582728 http://dx.doi.org/10.1107/S1600536809023149 Text en © Dong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Dong, Wen-Kui Wu, Jian-Chao Yao, Jian Gong, Shang-Sheng Tong, Jun-Feng {2,2′-[1,1′-(Ethylenedioxydinitrilo)diethylidyne]di-1-naphtholato}nickel(II) |
title | {2,2′-[1,1′-(Ethylenedioxydinitrilo)diethylidyne]di-1-naphtholato}nickel(II) |
title_full | {2,2′-[1,1′-(Ethylenedioxydinitrilo)diethylidyne]di-1-naphtholato}nickel(II) |
title_fullStr | {2,2′-[1,1′-(Ethylenedioxydinitrilo)diethylidyne]di-1-naphtholato}nickel(II) |
title_full_unstemmed | {2,2′-[1,1′-(Ethylenedioxydinitrilo)diethylidyne]di-1-naphtholato}nickel(II) |
title_short | {2,2′-[1,1′-(Ethylenedioxydinitrilo)diethylidyne]di-1-naphtholato}nickel(II) |
title_sort | {2,2′-[1,1′-(ethylenedioxydinitrilo)diethylidyne]di-1-naphtholato}nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969427/ https://www.ncbi.nlm.nih.gov/pubmed/21582728 http://dx.doi.org/10.1107/S1600536809023149 |
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