2,4-Dichloro-N-o-tolyl­benzamide

In the title compound, C(14)H(11)Cl(2)NO, the central C—C(O)—N—C amide unit makes dihedral angles of 68.71 (11) and 54.92 (12)°, respectively, with the dichloro­benzene and tolyl rings. The two aromatic rings are inclined at 16.25 (17)°. In the crystal, N—H⋯O hydrogen bonds link mol­ecules into zigz...

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Detalles Bibliográficos
Autores principales: Saeed, Aamer, Khera, Rasheed Ahmad, Simpson, Jim, Stanley, Roderick G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969429/
https://www.ncbi.nlm.nih.gov/pubmed/21582906
http://dx.doi.org/10.1107/S1600536809022752
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author Saeed, Aamer
Khera, Rasheed Ahmad
Simpson, Jim
Stanley, Roderick G.
author_facet Saeed, Aamer
Khera, Rasheed Ahmad
Simpson, Jim
Stanley, Roderick G.
author_sort Saeed, Aamer
collection PubMed
description In the title compound, C(14)H(11)Cl(2)NO, the central C—C(O)—N—C amide unit makes dihedral angles of 68.71 (11) and 54.92 (12)°, respectively, with the dichloro­benzene and tolyl rings. The two aromatic rings are inclined at 16.25 (17)°. In the crystal, N—H⋯O hydrogen bonds link mol­ecules into zigzag chains propagating in [001]. C—H⋯Cl contacts link these chains and additional C—H⋯O contacts generate stacks down b. Weak C—H⋯π and C—Cl⋯π inter­actions [Cl⋯centroid distance = 3.5422 (15) Å] may also stabilize the structure.
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spelling pubmed-29694292010-12-30 2,4-Dichloro-N-o-tolyl­benzamide Saeed, Aamer Khera, Rasheed Ahmad Simpson, Jim Stanley, Roderick G. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(11)Cl(2)NO, the central C—C(O)—N—C amide unit makes dihedral angles of 68.71 (11) and 54.92 (12)°, respectively, with the dichloro­benzene and tolyl rings. The two aromatic rings are inclined at 16.25 (17)°. In the crystal, N—H⋯O hydrogen bonds link mol­ecules into zigzag chains propagating in [001]. C—H⋯Cl contacts link these chains and additional C—H⋯O contacts generate stacks down b. Weak C—H⋯π and C—Cl⋯π inter­actions [Cl⋯centroid distance = 3.5422 (15) Å] may also stabilize the structure. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969429/ /pubmed/21582906 http://dx.doi.org/10.1107/S1600536809022752 Text en © Saeed et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Saeed, Aamer
Khera, Rasheed Ahmad
Simpson, Jim
Stanley, Roderick G.
2,4-Dichloro-N-o-tolyl­benzamide
title 2,4-Dichloro-N-o-tolyl­benzamide
title_full 2,4-Dichloro-N-o-tolyl­benzamide
title_fullStr 2,4-Dichloro-N-o-tolyl­benzamide
title_full_unstemmed 2,4-Dichloro-N-o-tolyl­benzamide
title_short 2,4-Dichloro-N-o-tolyl­benzamide
title_sort 2,4-dichloro-n-o-tolyl­benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969429/
https://www.ncbi.nlm.nih.gov/pubmed/21582906
http://dx.doi.org/10.1107/S1600536809022752
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AT kherarasheedahmad 24dichloronotolylbenzamide
AT simpsonjim 24dichloronotolylbenzamide
AT stanleyroderickg 24dichloronotolylbenzamide

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