Cargando…
Diaquabis(2-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN (1))nickel(II)
In the monomeric centrosymmetric title Ni(II) complex, [Ni(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center. The asymmetric unit contains one 2-bromobenzoate ligand, one diethylnicotinamide (DENA) ligand and one coordinated water molecule. The fo...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969431/ https://www.ncbi.nlm.nih.gov/pubmed/21582698 http://dx.doi.org/10.1107/S1600536809021795 |
Sumario: | In the monomeric centrosymmetric title Ni(II) complex, [Ni(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center. The asymmetric unit contains one 2-bromobenzoate ligand, one diethylnicotinamide (DENA) ligand and one coordinated water molecule. The four O atoms in the equatorial plane around the Ni(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by two N atoms of two DENA ligands in the axial positions. The dihedral angle between the benzene ring and the attached carboxylate group is 87.73 (15)°, while the pyridine and benzene rings are oriented at a dihedral angle of 42.48 (7)°. In the crystal structure, O—H⋯O hydrogen bonds link the molecules into a two-dimensional network parallel to (10[Image: see text]). In addition, C—H⋯O hydrogen bonds are observed. |
---|