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Diaqua­bis(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))nickel(II)

In the monomeric centrosymmetric title Ni(II) complex, [Ni(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center. The asymmetric unit contains one 2-bromo­benzoate ligand, one diethyl­nicotinamide (DENA) ligand and one coordinated water mol­ecule. The fo...

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Autores principales: Hökelek, Tuncer, Yılmaz, Filiz, Tercan, Barış, Özbek, F. Elif, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969431/
https://www.ncbi.nlm.nih.gov/pubmed/21582698
http://dx.doi.org/10.1107/S1600536809021795
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author Hökelek, Tuncer
Yılmaz, Filiz
Tercan, Barış
Özbek, F. Elif
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Yılmaz, Filiz
Tercan, Barış
Özbek, F. Elif
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description In the monomeric centrosymmetric title Ni(II) complex, [Ni(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center. The asymmetric unit contains one 2-bromo­benzoate ligand, one diethyl­nicotinamide (DENA) ligand and one coordinated water mol­ecule. The four O atoms in the equatorial plane around the Ni(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by two N atoms of two DENA ligands in the axial positions. The dihedral angle between the benzene ring and the attached carboxyl­ate group is 87.73 (15)°, while the pyridine and benzene rings are oriented at a dihedral angle of 42.48 (7)°. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network parallel to (10[Image: see text]). In addition, C—H⋯O hydrogen bonds are observed.
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spelling pubmed-29694312010-12-30 Diaqua­bis(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))nickel(II) Hökelek, Tuncer Yılmaz, Filiz Tercan, Barış Özbek, F. Elif Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the monomeric centrosymmetric title Ni(II) complex, [Ni(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center. The asymmetric unit contains one 2-bromo­benzoate ligand, one diethyl­nicotinamide (DENA) ligand and one coordinated water mol­ecule. The four O atoms in the equatorial plane around the Ni(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by two N atoms of two DENA ligands in the axial positions. The dihedral angle between the benzene ring and the attached carboxyl­ate group is 87.73 (15)°, while the pyridine and benzene rings are oriented at a dihedral angle of 42.48 (7)°. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network parallel to (10[Image: see text]). In addition, C—H⋯O hydrogen bonds are observed. International Union of Crystallography 2009-06-13 /pmc/articles/PMC2969431/ /pubmed/21582698 http://dx.doi.org/10.1107/S1600536809021795 Text en © Hökelek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Yılmaz, Filiz
Tercan, Barış
Özbek, F. Elif
Necefoğlu, Hacali
Diaqua­bis(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))nickel(II)
title Diaqua­bis(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))nickel(II)
title_full Diaqua­bis(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))nickel(II)
title_fullStr Diaqua­bis(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))nickel(II)
title_full_unstemmed Diaqua­bis(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))nickel(II)
title_short Diaqua­bis(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))nickel(II)
title_sort diaqua­bis(2-bromo­benzoato-κo)bis­(n,n-diethyl­nicotinamide-κn (1))nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969431/
https://www.ncbi.nlm.nih.gov/pubmed/21582698
http://dx.doi.org/10.1107/S1600536809021795
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