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Diaquabis(2-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN (1))nickel(II)
In the monomeric centrosymmetric title Ni(II) complex, [Ni(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center. The asymmetric unit contains one 2-bromobenzoate ligand, one diethylnicotinamide (DENA) ligand and one coordinated water molecule. The fo...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969431/ https://www.ncbi.nlm.nih.gov/pubmed/21582698 http://dx.doi.org/10.1107/S1600536809021795 |
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author | Hökelek, Tuncer Yılmaz, Filiz Tercan, Barış Özbek, F. Elif Necefoğlu, Hacali |
author_facet | Hökelek, Tuncer Yılmaz, Filiz Tercan, Barış Özbek, F. Elif Necefoğlu, Hacali |
author_sort | Hökelek, Tuncer |
collection | PubMed |
description | In the monomeric centrosymmetric title Ni(II) complex, [Ni(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center. The asymmetric unit contains one 2-bromobenzoate ligand, one diethylnicotinamide (DENA) ligand and one coordinated water molecule. The four O atoms in the equatorial plane around the Ni(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by two N atoms of two DENA ligands in the axial positions. The dihedral angle between the benzene ring and the attached carboxylate group is 87.73 (15)°, while the pyridine and benzene rings are oriented at a dihedral angle of 42.48 (7)°. In the crystal structure, O—H⋯O hydrogen bonds link the molecules into a two-dimensional network parallel to (10[Image: see text]). In addition, C—H⋯O hydrogen bonds are observed. |
format | Text |
id | pubmed-2969431 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29694312010-12-30 Diaquabis(2-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN (1))nickel(II) Hökelek, Tuncer Yılmaz, Filiz Tercan, Barış Özbek, F. Elif Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the monomeric centrosymmetric title Ni(II) complex, [Ni(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center. The asymmetric unit contains one 2-bromobenzoate ligand, one diethylnicotinamide (DENA) ligand and one coordinated water molecule. The four O atoms in the equatorial plane around the Ni(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by two N atoms of two DENA ligands in the axial positions. The dihedral angle between the benzene ring and the attached carboxylate group is 87.73 (15)°, while the pyridine and benzene rings are oriented at a dihedral angle of 42.48 (7)°. In the crystal structure, O—H⋯O hydrogen bonds link the molecules into a two-dimensional network parallel to (10[Image: see text]). In addition, C—H⋯O hydrogen bonds are observed. International Union of Crystallography 2009-06-13 /pmc/articles/PMC2969431/ /pubmed/21582698 http://dx.doi.org/10.1107/S1600536809021795 Text en © Hökelek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hökelek, Tuncer Yılmaz, Filiz Tercan, Barış Özbek, F. Elif Necefoğlu, Hacali Diaquabis(2-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN (1))nickel(II) |
title | Diaquabis(2-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN
(1))nickel(II) |
title_full | Diaquabis(2-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN
(1))nickel(II) |
title_fullStr | Diaquabis(2-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN
(1))nickel(II) |
title_full_unstemmed | Diaquabis(2-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN
(1))nickel(II) |
title_short | Diaquabis(2-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN
(1))nickel(II) |
title_sort | diaquabis(2-bromobenzoato-κo)bis(n,n-diethylnicotinamide-κn
(1))nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969431/ https://www.ncbi.nlm.nih.gov/pubmed/21582698 http://dx.doi.org/10.1107/S1600536809021795 |
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