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2-(5,6-Di­hydro­benzimidazolo[1,2-c]quinazolin-6-yl)aniline methanol solvate

In the structure of the title compound, C(20)H(16)N(4)·CH(4)O, the aniline ring forms dihedral angles of 89.9 (2) and 85.4 (2)° with the benzimidazole and benzene rings, respectively. The orientation of the aniline ring is mainly determined by strong hydrogen bonds between the amino group and the no...

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Detalles Bibliográficos
Autores principales: Booysen, Irvin, Gerber, Thomas I. A., Hosten, Eric, Mayer, Peter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969432/
https://www.ncbi.nlm.nih.gov/pubmed/21582846
http://dx.doi.org/10.1107/S1600536809021886
Descripción
Sumario:In the structure of the title compound, C(20)H(16)N(4)·CH(4)O, the aniline ring forms dihedral angles of 89.9 (2) and 85.4 (2)° with the benzimidazole and benzene rings, respectively. The orientation of the aniline ring is mainly determined by strong hydrogen bonds between the amino group and the non-fused quinazoline N atom. Inter­molecular hydrogen bonds of the N—H⋯N—H⋯N type along [010] and the N—H⋯O—H⋯N type along [100] are formed, resulting in C (2) (2)(4) and C (2) (2)(10) descriptors, respectively, on a binary level of graph-set analysis. There are C—H⋯π contacts with H⋯π distances of 2.44 Å; however, no π-stacking is observed.