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2,3-Diamino­pyridinium 4-nitro­benzoate

In the title salt, C(5)H(8)N(3) (+)·C(7)H(4)NO(4) (−), the pyridine N atom of the 2,3-diamino­pyridine mol­ecule is protonated. The protonated N atom and one of the two 2-amino groups are hydrogen bonded to the 4-nitro­benzoate anion through a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ri...

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Detalles Bibliográficos
Autores principales: Balasubramani, Kasthuri, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969435/
https://www.ncbi.nlm.nih.gov/pubmed/21582806
http://dx.doi.org/10.1107/S160053680902100X
Descripción
Sumario:In the title salt, C(5)H(8)N(3) (+)·C(7)H(4)NO(4) (−), the pyridine N atom of the 2,3-diamino­pyridine mol­ecule is protonated. The protonated N atom and one of the two 2-amino groups are hydrogen bonded to the 4-nitro­benzoate anion through a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The carboxyl­ate mean plane of the 4-nitro­benzoate anion is twisted by 3.77 (5)° from the attached ring and the nitro group is similarly twisted by 2.28 (10)°. In the crystal, the mol­ecules are linked by N—H⋯O and C—H⋯O inter­actions into sheets parallel to (100).