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2,3-Diaminopyridinium 4-nitrobenzoate
In the title salt, C(5)H(8)N(3) (+)·C(7)H(4)NO(4) (−), the pyridine N atom of the 2,3-diaminopyridine molecule is protonated. The protonated N atom and one of the two 2-amino groups are hydrogen bonded to the 4-nitrobenzoate anion through a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ri...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969435/ https://www.ncbi.nlm.nih.gov/pubmed/21582806 http://dx.doi.org/10.1107/S160053680902100X |
Sumario: | In the title salt, C(5)H(8)N(3) (+)·C(7)H(4)NO(4) (−), the pyridine N atom of the 2,3-diaminopyridine molecule is protonated. The protonated N atom and one of the two 2-amino groups are hydrogen bonded to the 4-nitrobenzoate anion through a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The carboxylate mean plane of the 4-nitrobenzoate anion is twisted by 3.77 (5)° from the attached ring and the nitro group is similarly twisted by 2.28 (10)°. In the crystal, the molecules are linked by N—H⋯O and C—H⋯O interactions into sheets parallel to (100). |
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