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catena-Poly[lead(II)-[μ-2,4-diamino-6-(piperidin-1-yl)pyrimidine N-oxide-κ(2) O:O]di-μ-iodido]
The N-oxide O atom of the minoxidil unit in the 1/1 adduct with lead(II) iodide, [PbI(2)(C(9)H(15)N(5)O)](n), bridges two Pb(II) atoms, as do each of the I atoms. The bridging interactions give rise to a linear chain motif that propagates along the a axis of the orthorhombic unit cell. The coordi...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969437/ https://www.ncbi.nlm.nih.gov/pubmed/21582686 http://dx.doi.org/10.1107/S1600536809020972 |
Sumario: | The N-oxide O atom of the minoxidil unit in the 1/1 adduct with lead(II) iodide, [PbI(2)(C(9)H(15)N(5)O)](n), bridges two Pb(II) atoms, as do each of the I atoms. The bridging interactions give rise to a linear chain motif that propagates along the a axis of the orthorhombic unit cell. The coordination sphere around the six-coordinate Pb(II) atom is a distorted ψ-monocapped octahedron in which the stereochemically active lone pair caps one of the faces defined by the O and I atoms forming the longer Pb—O or Pb—I bonds. The Pb(II) atom lies on a mirror plane; the mirror plane is perpendicular to the pyrimidine ring and it bisects the piperidine ring. The aromatic ring is disordered about the mirror plane with respect to the 1-nitrogen and 5-carbon atoms. |
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