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catena-Poly[lead(II)-[μ-2,4-diamino-6-(piperidin-1-yl)pyrimidine N-oxide-κ(2) O:O]di-μ-iodido]

The N-oxide O atom of the minoxidil unit in the 1/1 adduct with lead(II) iodide, [PbI(2)(C(9)H(15)N(5)O)](n), bridges two Pb(II) atoms, as do each of the I atoms. The bridging inter­actions give rise to a linear chain motif that propagates along the a axis of the ortho­rhom­bic unit cell. The coordi...

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Detalles Bibliográficos
Autores principales: Ranjbar, Maryam, Najafi, S. Heidar Mahmoudi, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969437/
https://www.ncbi.nlm.nih.gov/pubmed/21582686
http://dx.doi.org/10.1107/S1600536809020972
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author Ranjbar, Maryam
Najafi, S. Heidar Mahmoudi
Ng, Seik Weng
author_facet Ranjbar, Maryam
Najafi, S. Heidar Mahmoudi
Ng, Seik Weng
author_sort Ranjbar, Maryam
collection PubMed
description The N-oxide O atom of the minoxidil unit in the 1/1 adduct with lead(II) iodide, [PbI(2)(C(9)H(15)N(5)O)](n), bridges two Pb(II) atoms, as do each of the I atoms. The bridging inter­actions give rise to a linear chain motif that propagates along the a axis of the ortho­rhom­bic unit cell. The coordination sphere around the six-coordinate Pb(II) atom is a distorted ψ-monocapped octa­hedron in which the stereochemically active lone pair caps one of the faces defined by the O and I atoms forming the longer Pb—O or Pb—I bonds. The Pb(II) atom lies on a mirror plane; the mirror plane is perpendicular to the pyrimidine ring and it bis­ects the piperidine ring. The aromatic ring is disordered about the mirror plane with respect to the 1-nitro­gen and 5-carbon atoms.
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spelling pubmed-29694372010-12-30 catena-Poly[lead(II)-[μ-2,4-diamino-6-(piperidin-1-yl)pyrimidine N-oxide-κ(2) O:O]di-μ-iodido] Ranjbar, Maryam Najafi, S. Heidar Mahmoudi Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The N-oxide O atom of the minoxidil unit in the 1/1 adduct with lead(II) iodide, [PbI(2)(C(9)H(15)N(5)O)](n), bridges two Pb(II) atoms, as do each of the I atoms. The bridging inter­actions give rise to a linear chain motif that propagates along the a axis of the ortho­rhom­bic unit cell. The coordination sphere around the six-coordinate Pb(II) atom is a distorted ψ-monocapped octa­hedron in which the stereochemically active lone pair caps one of the faces defined by the O and I atoms forming the longer Pb—O or Pb—I bonds. The Pb(II) atom lies on a mirror plane; the mirror plane is perpendicular to the pyrimidine ring and it bis­ects the piperidine ring. The aromatic ring is disordered about the mirror plane with respect to the 1-nitro­gen and 5-carbon atoms. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969437/ /pubmed/21582686 http://dx.doi.org/10.1107/S1600536809020972 Text en © Ranjbar et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ranjbar, Maryam
Najafi, S. Heidar Mahmoudi
Ng, Seik Weng
catena-Poly[lead(II)-[μ-2,4-diamino-6-(piperidin-1-yl)pyrimidine N-oxide-κ(2) O:O]di-μ-iodido]
title catena-Poly[lead(II)-[μ-2,4-diamino-6-(piperidin-1-yl)pyrimidine N-oxide-κ(2) O:O]di-μ-iodido]
title_full catena-Poly[lead(II)-[μ-2,4-diamino-6-(piperidin-1-yl)pyrimidine N-oxide-κ(2) O:O]di-μ-iodido]
title_fullStr catena-Poly[lead(II)-[μ-2,4-diamino-6-(piperidin-1-yl)pyrimidine N-oxide-κ(2) O:O]di-μ-iodido]
title_full_unstemmed catena-Poly[lead(II)-[μ-2,4-diamino-6-(piperidin-1-yl)pyrimidine N-oxide-κ(2) O:O]di-μ-iodido]
title_short catena-Poly[lead(II)-[μ-2,4-diamino-6-(piperidin-1-yl)pyrimidine N-oxide-κ(2) O:O]di-μ-iodido]
title_sort catena-poly[lead(ii)-[μ-2,4-diamino-6-(piperidin-1-yl)pyrimidine n-oxide-κ(2) o:o]di-μ-iodido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969437/
https://www.ncbi.nlm.nih.gov/pubmed/21582686
http://dx.doi.org/10.1107/S1600536809020972
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