Ethyl 2-[(2,6-dimethyl­phen­yl)hydrazono]-3-oxobutanoate

The title compound, C(14)H(18)N(2)O(3), crystallizes with two independent mol­ecules in the asymmetric unit, having closely comparable geometries. Both mol­ecules are essentially planar [maximum deviations from the mean plane of 0.069 (1) and 0.068 (1) Å for the two mol­ecules] and contain an intra­...

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Autores principales: Fun, Hoong-Kun, Jebas, Samuel Robinson, Padaki, Mahesh, Hegde, Chitrakar, Isloor, Arun M
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969439/
https://www.ncbi.nlm.nih.gov/pubmed/21582829
http://dx.doi.org/10.1107/S160053680902131X
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author Fun, Hoong-Kun
Jebas, Samuel Robinson
Padaki, Mahesh
Hegde, Chitrakar
Isloor, Arun M
author_facet Fun, Hoong-Kun
Jebas, Samuel Robinson
Padaki, Mahesh
Hegde, Chitrakar
Isloor, Arun M
author_sort Fun, Hoong-Kun
collection PubMed
description The title compound, C(14)H(18)N(2)O(3), crystallizes with two independent mol­ecules in the asymmetric unit, having closely comparable geometries. Both mol­ecules are essentially planar [maximum deviations from the mean plane of 0.069 (1) and 0.068 (1) Å for the two mol­ecules] and contain an intra­molecular N—H⋯O hydrogen bond which generates a ring with graph-set motif S(6). In the crystal, the mol­ecules are linked into chains along the c axis by inter­molecular C—H⋯O hydrogen bonds, and inter­molecular C—H⋯π inter­actions are also present.
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spelling pubmed-29694392010-12-30 Ethyl 2-[(2,6-dimethyl­phen­yl)hydrazono]-3-oxobutanoate Fun, Hoong-Kun Jebas, Samuel Robinson Padaki, Mahesh Hegde, Chitrakar Isloor, Arun M Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(18)N(2)O(3), crystallizes with two independent mol­ecules in the asymmetric unit, having closely comparable geometries. Both mol­ecules are essentially planar [maximum deviations from the mean plane of 0.069 (1) and 0.068 (1) Å for the two mol­ecules] and contain an intra­molecular N—H⋯O hydrogen bond which generates a ring with graph-set motif S(6). In the crystal, the mol­ecules are linked into chains along the c axis by inter­molecular C—H⋯O hydrogen bonds, and inter­molecular C—H⋯π inter­actions are also present. International Union of Crystallography 2009-06-10 /pmc/articles/PMC2969439/ /pubmed/21582829 http://dx.doi.org/10.1107/S160053680902131X Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Jebas, Samuel Robinson
Padaki, Mahesh
Hegde, Chitrakar
Isloor, Arun M
Ethyl 2-[(2,6-dimethyl­phen­yl)hydrazono]-3-oxobutanoate
title Ethyl 2-[(2,6-dimethyl­phen­yl)hydrazono]-3-oxobutanoate
title_full Ethyl 2-[(2,6-dimethyl­phen­yl)hydrazono]-3-oxobutanoate
title_fullStr Ethyl 2-[(2,6-dimethyl­phen­yl)hydrazono]-3-oxobutanoate
title_full_unstemmed Ethyl 2-[(2,6-dimethyl­phen­yl)hydrazono]-3-oxobutanoate
title_short Ethyl 2-[(2,6-dimethyl­phen­yl)hydrazono]-3-oxobutanoate
title_sort ethyl 2-[(2,6-dimethyl­phen­yl)hydrazono]-3-oxobutanoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969439/
https://www.ncbi.nlm.nih.gov/pubmed/21582829
http://dx.doi.org/10.1107/S160053680902131X
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AT hegdechitrakar ethyl226dimethylphenylhydrazono3oxobutanoate
AT isloorarunm ethyl226dimethylphenylhydrazono3oxobutanoate

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