N-(9H-Fluoren-9-yl­idene)-4-methyl­aniline

In the title compound, C(20)H(15)N, the fluorene unit is essentially planar [r.m.s. deviation 0.0334 Å] and the benzene ring bound to the imine N atom bears a methyl group which is nearly coplanar [dihedral angle 0.5 (1)°]. The dihedral angle between the substituent benzene ring and the 9H-fluoren-9...

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Detalles Bibliográficos
Autores principales: Bai, Su-Zhen, Lou, Xin-Hua, Li, Hong-Mei, Shi, Hui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969441/
https://www.ncbi.nlm.nih.gov/pubmed/21582831
http://dx.doi.org/10.1107/S1600536809020765
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author Bai, Su-Zhen
Lou, Xin-Hua
Li, Hong-Mei
Shi, Hui
author_facet Bai, Su-Zhen
Lou, Xin-Hua
Li, Hong-Mei
Shi, Hui
author_sort Bai, Su-Zhen
collection PubMed
description In the title compound, C(20)H(15)N, the fluorene unit is essentially planar [r.m.s. deviation 0.0334 Å] and the benzene ring bound to the imine N atom bears a methyl group which is nearly coplanar [dihedral angle 0.5 (1)°]. The dihedral angle between the substituent benzene ring and the 9H-fluoren-9-imine unit is 71.1 (3)°. Inter­molecular π–π inter­actions between the benzene rings of adjacent fluorene units [centroid–centroid distance 3.8081 (13) Å] are present in the crystal structure, resulting in a one-dimensional supra­molecular architecture.
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spelling pubmed-29694412010-12-30 N-(9H-Fluoren-9-yl­idene)-4-methyl­aniline Bai, Su-Zhen Lou, Xin-Hua Li, Hong-Mei Shi, Hui Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(15)N, the fluorene unit is essentially planar [r.m.s. deviation 0.0334 Å] and the benzene ring bound to the imine N atom bears a methyl group which is nearly coplanar [dihedral angle 0.5 (1)°]. The dihedral angle between the substituent benzene ring and the 9H-fluoren-9-imine unit is 71.1 (3)°. Inter­molecular π–π inter­actions between the benzene rings of adjacent fluorene units [centroid–centroid distance 3.8081 (13) Å] are present in the crystal structure, resulting in a one-dimensional supra­molecular architecture. International Union of Crystallography 2009-06-10 /pmc/articles/PMC2969441/ /pubmed/21582831 http://dx.doi.org/10.1107/S1600536809020765 Text en © Bai et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bai, Su-Zhen
Lou, Xin-Hua
Li, Hong-Mei
Shi, Hui
N-(9H-Fluoren-9-yl­idene)-4-methyl­aniline
title N-(9H-Fluoren-9-yl­idene)-4-methyl­aniline
title_full N-(9H-Fluoren-9-yl­idene)-4-methyl­aniline
title_fullStr N-(9H-Fluoren-9-yl­idene)-4-methyl­aniline
title_full_unstemmed N-(9H-Fluoren-9-yl­idene)-4-methyl­aniline
title_short N-(9H-Fluoren-9-yl­idene)-4-methyl­aniline
title_sort n-(9h-fluoren-9-yl­idene)-4-methyl­aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969441/
https://www.ncbi.nlm.nih.gov/pubmed/21582831
http://dx.doi.org/10.1107/S1600536809020765
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