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(Acetone-2κO){μ-6,6′-dimeth­oxy-2,2′-[propane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(8)1:2O (6),O (1),O (1′),O (6′):O (1),N,N′,O (1′)}tris­(nitrato-1κ(2) O,O′)copper(II)samarium(III)

In the title heteronuclear complex, [CuSm(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)COCH(3))], the Cu(II) ion is five-coordinated by two O and two N atoms from the 6,6′-dimeth­oxy-2,2′-[propane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolate ligand (L) and by an O atom from the acetone mol­ecule in a square-...

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Detalles Bibliográficos
Autores principales: Sun, Wen-Bin, Yan, Peng-Fei, Li, Hong-Feng, Gao, Ting, Li, Guang-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969449/
https://www.ncbi.nlm.nih.gov/pubmed/21582755
http://dx.doi.org/10.1107/S160053680902399X
Descripción
Sumario:In the title heteronuclear complex, [CuSm(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)COCH(3))], the Cu(II) ion is five-coordinated by two O and two N atoms from the 6,6′-dimeth­oxy-2,2′-[propane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolate ligand (L) and by an O atom from the acetone mol­ecule in a square-pyramidal geometry. The Sm(III) ion is ten-coordinated by six O atoms from the three nitrate ligands and four O atoms from the L ligand. In L, the C atoms of the diamino­propane fragment are disordered over two positions in a 0.674 (10):0.326 (10) ratio.