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(Acetone-2κO){μ-6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(8)1:2O (6),O (1),O (1′),O (6′):O (1),N,N′,O (1′)}tris(nitrato-1κ(2) O,O′)copper(II)samarium(III)
In the title heteronuclear complex, [CuSm(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)COCH(3))], the Cu(II) ion is five-coordinated by two O and two N atoms from the 6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolate ligand (L) and by an O atom from the acetone molecule in a square-...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969449/ https://www.ncbi.nlm.nih.gov/pubmed/21582755 http://dx.doi.org/10.1107/S160053680902399X |
Sumario: | In the title heteronuclear complex, [CuSm(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)COCH(3))], the Cu(II) ion is five-coordinated by two O and two N atoms from the 6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolate ligand (L) and by an O atom from the acetone molecule in a square-pyramidal geometry. The Sm(III) ion is ten-coordinated by six O atoms from the three nitrate ligands and four O atoms from the L ligand. In L, the C atoms of the diaminopropane fragment are disordered over two positions in a 0.674 (10):0.326 (10) ratio. |
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