[Tris(3,5-diphenyl­pyrazol­yl)hydro­borato]nickel(II) bromide

In the title tris­(pyrazol­yl)borate (Tp(Ph2)) complex, [NiBr(C(45)H(34)BN(6))], the Ni, Br and B atoms lie on a crystallographic threefold axis and a distorted NiN(3)Br tetra­hedral geometry arises for the metal ion. In the crystal, C—H⋯(C=C) and C—H⋯π inter­actions help to establish the polar crys...

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Detalles Bibliográficos
Autores principales: Harding, David J., Harding, Phimphaka, Adams, Harry
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969450/
https://www.ncbi.nlm.nih.gov/pubmed/21582703
http://dx.doi.org/10.1107/S1600536809021606
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author Harding, David J.
Harding, Phimphaka
Adams, Harry
author_facet Harding, David J.
Harding, Phimphaka
Adams, Harry
author_sort Harding, David J.
collection PubMed
description In the title tris­(pyrazol­yl)borate (Tp(Ph2)) complex, [NiBr(C(45)H(34)BN(6))], the Ni, Br and B atoms lie on a crystallographic threefold axis and a distorted NiN(3)Br tetra­hedral geometry arises for the metal ion. In the crystal, C—H⋯(C=C) and C—H⋯π inter­actions help to establish the polar crystal packing.
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spelling pubmed-29694502010-12-30 [Tris(3,5-diphenyl­pyrazol­yl)hydro­borato]nickel(II) bromide Harding, David J. Harding, Phimphaka Adams, Harry Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title tris­(pyrazol­yl)borate (Tp(Ph2)) complex, [NiBr(C(45)H(34)BN(6))], the Ni, Br and B atoms lie on a crystallographic threefold axis and a distorted NiN(3)Br tetra­hedral geometry arises for the metal ion. In the crystal, C—H⋯(C=C) and C—H⋯π inter­actions help to establish the polar crystal packing. International Union of Crystallography 2009-06-13 /pmc/articles/PMC2969450/ /pubmed/21582703 http://dx.doi.org/10.1107/S1600536809021606 Text en © Harding et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Harding, David J.
Harding, Phimphaka
Adams, Harry
[Tris(3,5-diphenyl­pyrazol­yl)hydro­borato]nickel(II) bromide
title [Tris(3,5-diphenyl­pyrazol­yl)hydro­borato]nickel(II) bromide
title_full [Tris(3,5-diphenyl­pyrazol­yl)hydro­borato]nickel(II) bromide
title_fullStr [Tris(3,5-diphenyl­pyrazol­yl)hydro­borato]nickel(II) bromide
title_full_unstemmed [Tris(3,5-diphenyl­pyrazol­yl)hydro­borato]nickel(II) bromide
title_short [Tris(3,5-diphenyl­pyrazol­yl)hydro­borato]nickel(II) bromide
title_sort [tris(3,5-diphenyl­pyrazol­yl)hydro­borato]nickel(ii) bromide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969450/
https://www.ncbi.nlm.nih.gov/pubmed/21582703
http://dx.doi.org/10.1107/S1600536809021606
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