Bis(thio­cyanato-κN)[tris­(2-pyridylmeth­yl)amine-κ(4) N,N′,N′′,N′′′]nickel(II) methanol hemisolvate

The title complex, [Ni(NCS)(2)(C(18)H(18)N(4))]·0.5CH(3)OH, consists of two crystallographically distinct complexes and a methanol solvent mol­ecule. The Ni(II) complexes are pseudo-octa­hedral six-coordinate, with the tris­(2-pyridylmeth­yl)amine (TPA) ligand providing four N atoms and two N-bound...

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Detalles Bibliográficos
Autores principales: Randeniya, Sajini R., Norman, Richard E.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969451/
https://www.ncbi.nlm.nih.gov/pubmed/21582701
http://dx.doi.org/10.1107/S1600536809021722
Descripción
Sumario:The title complex, [Ni(NCS)(2)(C(18)H(18)N(4))]·0.5CH(3)OH, consists of two crystallographically distinct complexes and a methanol solvent mol­ecule. The Ni(II) complexes are pseudo-octa­hedral six-coordinate, with the tris­(2-pyridylmeth­yl)amine (TPA) ligand providing four N atoms and two N-bound thio­cyanates providing the final two N atoms. The distances and angles are typical for Ni(II)–TPA complexes. The compound has unit-cell parameters that are surprisingly similar to the previously reported hydrate.

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