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2-Methyl-4,6-bis­(1-methyl­hydrazino)pyrimidine

In the title compound, C(7)H(14)N(6), the amine groups of the two methyl­hydrazino substituents are orientated in the opposite direction to the methyl substituent at the 2-position of the pyrimidine ring. The mol­ecule is almost planar with only the two amine N atoms lying substanti­ally out of the...

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Detalles Bibliográficos
Autores principales: Hutchinson, Daniel J., Hanton, Lyall R., Moratti, Stephen C.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969452/
https://www.ncbi.nlm.nih.gov/pubmed/21582832
http://dx.doi.org/10.1107/S1600536809021643
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author Hutchinson, Daniel J.
Hanton, Lyall R.
Moratti, Stephen C.
author_facet Hutchinson, Daniel J.
Hanton, Lyall R.
Moratti, Stephen C.
author_sort Hutchinson, Daniel J.
collection PubMed
description In the title compound, C(7)H(14)N(6), the amine groups of the two methyl­hydrazino substituents are orientated in the opposite direction to the methyl substituent at the 2-position of the pyrimidine ring. The mol­ecule is almost planar with only the two amine N atoms lying substanti­ally out of the mean plane of the pyrimidine ring [by 0.1430 (2) and 0.3092 (2) Å]. The H atoms on these amine groups point inwards towards the aromatic ring, such that the lone pair of electrons points outwards from the mol­ecule. Each mol­ecule is linked to two others through N—H⋯N hydrogen bonds between the two amino groups, forming a one-dimensional chain in the [010] direction. Offset face-to-face π–π stacking inter­actions between the pyrimidine rings organize these chains into a two-dimensional array [centroid–centroid distance = 3.789 (2) Å].
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spelling pubmed-29694522010-12-30 2-Methyl-4,6-bis­(1-methyl­hydrazino)pyrimidine Hutchinson, Daniel J. Hanton, Lyall R. Moratti, Stephen C. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(14)N(6), the amine groups of the two methyl­hydrazino substituents are orientated in the opposite direction to the methyl substituent at the 2-position of the pyrimidine ring. The mol­ecule is almost planar with only the two amine N atoms lying substanti­ally out of the mean plane of the pyrimidine ring [by 0.1430 (2) and 0.3092 (2) Å]. The H atoms on these amine groups point inwards towards the aromatic ring, such that the lone pair of electrons points outwards from the mol­ecule. Each mol­ecule is linked to two others through N—H⋯N hydrogen bonds between the two amino groups, forming a one-dimensional chain in the [010] direction. Offset face-to-face π–π stacking inter­actions between the pyrimidine rings organize these chains into a two-dimensional array [centroid–centroid distance = 3.789 (2) Å]. International Union of Crystallography 2009-06-10 /pmc/articles/PMC2969452/ /pubmed/21582832 http://dx.doi.org/10.1107/S1600536809021643 Text en © Hutchinson et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hutchinson, Daniel J.
Hanton, Lyall R.
Moratti, Stephen C.
2-Methyl-4,6-bis­(1-methyl­hydrazino)pyrimidine
title 2-Methyl-4,6-bis­(1-methyl­hydrazino)pyrimidine
title_full 2-Methyl-4,6-bis­(1-methyl­hydrazino)pyrimidine
title_fullStr 2-Methyl-4,6-bis­(1-methyl­hydrazino)pyrimidine
title_full_unstemmed 2-Methyl-4,6-bis­(1-methyl­hydrazino)pyrimidine
title_short 2-Methyl-4,6-bis­(1-methyl­hydrazino)pyrimidine
title_sort 2-methyl-4,6-bis­(1-methyl­hydrazino)pyrimidine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969452/
https://www.ncbi.nlm.nih.gov/pubmed/21582832
http://dx.doi.org/10.1107/S1600536809021643
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