Cargando…
2-Methyl-4,6-bis(1-methylhydrazino)pyrimidine
In the title compound, C(7)H(14)N(6), the amine groups of the two methylhydrazino substituents are orientated in the opposite direction to the methyl substituent at the 2-position of the pyrimidine ring. The molecule is almost planar with only the two amine N atoms lying substantially out of the...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969452/ https://www.ncbi.nlm.nih.gov/pubmed/21582832 http://dx.doi.org/10.1107/S1600536809021643 |
_version_ | 1782190154668048384 |
---|---|
author | Hutchinson, Daniel J. Hanton, Lyall R. Moratti, Stephen C. |
author_facet | Hutchinson, Daniel J. Hanton, Lyall R. Moratti, Stephen C. |
author_sort | Hutchinson, Daniel J. |
collection | PubMed |
description | In the title compound, C(7)H(14)N(6), the amine groups of the two methylhydrazino substituents are orientated in the opposite direction to the methyl substituent at the 2-position of the pyrimidine ring. The molecule is almost planar with only the two amine N atoms lying substantially out of the mean plane of the pyrimidine ring [by 0.1430 (2) and 0.3092 (2) Å]. The H atoms on these amine groups point inwards towards the aromatic ring, such that the lone pair of electrons points outwards from the molecule. Each molecule is linked to two others through N—H⋯N hydrogen bonds between the two amino groups, forming a one-dimensional chain in the [010] direction. Offset face-to-face π–π stacking interactions between the pyrimidine rings organize these chains into a two-dimensional array [centroid–centroid distance = 3.789 (2) Å]. |
format | Text |
id | pubmed-2969452 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29694522010-12-30 2-Methyl-4,6-bis(1-methylhydrazino)pyrimidine Hutchinson, Daniel J. Hanton, Lyall R. Moratti, Stephen C. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(14)N(6), the amine groups of the two methylhydrazino substituents are orientated in the opposite direction to the methyl substituent at the 2-position of the pyrimidine ring. The molecule is almost planar with only the two amine N atoms lying substantially out of the mean plane of the pyrimidine ring [by 0.1430 (2) and 0.3092 (2) Å]. The H atoms on these amine groups point inwards towards the aromatic ring, such that the lone pair of electrons points outwards from the molecule. Each molecule is linked to two others through N—H⋯N hydrogen bonds between the two amino groups, forming a one-dimensional chain in the [010] direction. Offset face-to-face π–π stacking interactions between the pyrimidine rings organize these chains into a two-dimensional array [centroid–centroid distance = 3.789 (2) Å]. International Union of Crystallography 2009-06-10 /pmc/articles/PMC2969452/ /pubmed/21582832 http://dx.doi.org/10.1107/S1600536809021643 Text en © Hutchinson et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hutchinson, Daniel J. Hanton, Lyall R. Moratti, Stephen C. 2-Methyl-4,6-bis(1-methylhydrazino)pyrimidine |
title | 2-Methyl-4,6-bis(1-methylhydrazino)pyrimidine |
title_full | 2-Methyl-4,6-bis(1-methylhydrazino)pyrimidine |
title_fullStr | 2-Methyl-4,6-bis(1-methylhydrazino)pyrimidine |
title_full_unstemmed | 2-Methyl-4,6-bis(1-methylhydrazino)pyrimidine |
title_short | 2-Methyl-4,6-bis(1-methylhydrazino)pyrimidine |
title_sort | 2-methyl-4,6-bis(1-methylhydrazino)pyrimidine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969452/ https://www.ncbi.nlm.nih.gov/pubmed/21582832 http://dx.doi.org/10.1107/S1600536809021643 |
work_keys_str_mv | AT hutchinsondanielj 2methyl46bis1methylhydrazinopyrimidine AT hantonlyallr 2methyl46bis1methylhydrazinopyrimidine AT morattistephenc 2methyl46bis1methylhydrazinopyrimidine |