3-exo-Chloro-8-oxabicyclo­[3.2.1]oct-6-ene-2,4-diol chloro­form 0.33-solvate

The title compound, 3C(7)H(9)ClO(3)·CHCl(3), crystallizes with mol­ecules of 3-exo-chloro-8-oxabicyclo­[3.2.1]oct-6-ene-2,4-diol (A) and chloro­form in a 3:1 ratio, in the space group R3m. Mol­ecules of A straddle a crystallographic mirror plane, whereas the chloro­form mol­ecules (C and H atoms) li...

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Autores principales: Tafeenko, Viktor A., Aslanov, Leonid A., Proskurnina, Marina V., Sosonyuk, Sergei E., Khlevin, Dmitrii A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969453/
https://www.ncbi.nlm.nih.gov/pubmed/21582856
http://dx.doi.org/10.1107/S1600536809021898
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author Tafeenko, Viktor A.
Aslanov, Leonid A.
Proskurnina, Marina V.
Sosonyuk, Sergei E.
Khlevin, Dmitrii A.
author_facet Tafeenko, Viktor A.
Aslanov, Leonid A.
Proskurnina, Marina V.
Sosonyuk, Sergei E.
Khlevin, Dmitrii A.
author_sort Tafeenko, Viktor A.
collection PubMed
description The title compound, 3C(7)H(9)ClO(3)·CHCl(3), crystallizes with mol­ecules of 3-exo-chloro-8-oxabicyclo­[3.2.1]oct-6-ene-2,4-diol (A) and chloro­form in a 3:1 ratio, in the space group R3m. Mol­ecules of A straddle a crystallographic mirror plane, whereas the chloro­form mol­ecules (C and H atoms) lie additionally on the threefold axis. The mol­ecules of A are linked into right- and left-helical chains by means of O—H⋯O hydrogen bonds, thus forming columns running along the c axis. Six inter­penetrated columns form a channel in which the solvent mol­ecules (chloro­form) are located.
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spelling pubmed-29694532010-12-30 3-exo-Chloro-8-oxabicyclo­[3.2.1]oct-6-ene-2,4-diol chloro­form 0.33-solvate Tafeenko, Viktor A. Aslanov, Leonid A. Proskurnina, Marina V. Sosonyuk, Sergei E. Khlevin, Dmitrii A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, 3C(7)H(9)ClO(3)·CHCl(3), crystallizes with mol­ecules of 3-exo-chloro-8-oxabicyclo­[3.2.1]oct-6-ene-2,4-diol (A) and chloro­form in a 3:1 ratio, in the space group R3m. Mol­ecules of A straddle a crystallographic mirror plane, whereas the chloro­form mol­ecules (C and H atoms) lie additionally on the threefold axis. The mol­ecules of A are linked into right- and left-helical chains by means of O—H⋯O hydrogen bonds, thus forming columns running along the c axis. Six inter­penetrated columns form a channel in which the solvent mol­ecules (chloro­form) are located. International Union of Crystallography 2009-06-13 /pmc/articles/PMC2969453/ /pubmed/21582856 http://dx.doi.org/10.1107/S1600536809021898 Text en © Tafeenko et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tafeenko, Viktor A.
Aslanov, Leonid A.
Proskurnina, Marina V.
Sosonyuk, Sergei E.
Khlevin, Dmitrii A.
3-exo-Chloro-8-oxabicyclo­[3.2.1]oct-6-ene-2,4-diol chloro­form 0.33-solvate
title 3-exo-Chloro-8-oxabicyclo­[3.2.1]oct-6-ene-2,4-diol chloro­form 0.33-solvate
title_full 3-exo-Chloro-8-oxabicyclo­[3.2.1]oct-6-ene-2,4-diol chloro­form 0.33-solvate
title_fullStr 3-exo-Chloro-8-oxabicyclo­[3.2.1]oct-6-ene-2,4-diol chloro­form 0.33-solvate
title_full_unstemmed 3-exo-Chloro-8-oxabicyclo­[3.2.1]oct-6-ene-2,4-diol chloro­form 0.33-solvate
title_short 3-exo-Chloro-8-oxabicyclo­[3.2.1]oct-6-ene-2,4-diol chloro­form 0.33-solvate
title_sort 3-exo-chloro-8-oxabicyclo­[3.2.1]oct-6-ene-2,4-diol chloro­form 0.33-solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969453/
https://www.ncbi.nlm.nih.gov/pubmed/21582856
http://dx.doi.org/10.1107/S1600536809021898
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