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(E)-Methyl N′-(2-hydr­oxy-3-methoxy­benzyl­idene)hydrazinecarboxyl­ate

The title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The non-H atoms of the mol­ecule are essentially coplanar, with a maximum deviation of 0.015 (2) Å. An intra­molecular O—H⋯N inter­action is observed. In the crystal structure, the mol­ecules ar...

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Detalles Bibliográficos
Autores principales: Lv, Lu-Ping, Yu, Wen-Bo, Li, Wei-Wei, Zhang, Yong-Zhao, Hu, Xian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969457/
https://www.ncbi.nlm.nih.gov/pubmed/21582834
http://dx.doi.org/10.1107/S1600536809021631
Descripción
Sumario:The title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The non-H atoms of the mol­ecule are essentially coplanar, with a maximum deviation of 0.015 (2) Å. An intra­molecular O—H⋯N inter­action is observed. In the crystal structure, the mol­ecules are linked into a two-dimensional network parallel to the ac plane by N—H⋯O hydrogen bonds involving the meth­oxy O atom and by two C—H⋯O hydrogen bonds involving the carbonyl O atom. In addition, an intermolecular C—H⋯π inter­action is observed.